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Sun, Jinhua
Publications (9 of 9) Show all publications
Sun, J., Ma, J., Fan, J., Pyun, J. & Geng, J. (2019). Rational design of sulfur-containing composites for high-performance lithium-sulfur batteries. APL MATERIALS, 7(2), Article ID 020904.
Open this publication in new window or tab >>Rational design of sulfur-containing composites for high-performance lithium-sulfur batteries
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2019 (English)In: APL MATERIALS, ISSN 2166-532X, Vol. 7, no 2, article id 020904Article in journal (Refereed) Published
Abstract [en]

Sulfur has received considerable attention as a cathode material for lithium-sulfur (Li-S) batteries due to its high theoretical energy density (2567 W h kg(-1)), high earth abundance, and environmental benignity. However, the insulating nature of sulfur and the shuttle effect of soluble lithium polysulfides result in serious technical issues, such as low utilization rate of sulfur, reduced columbic efficiency, and poor cycling stability, which compromise the high theoretical performance of Li-S batteries. In the past years, various attempts have been made to achieve high specific capacity and reliable cycling stability of Li-S batteries. Incorporation of sulfur into functional host materials has been demonstrated to be effective to improve the electrochemical performance of sulfur-based cathodes via enhancing the electron and Li ion conductivities, immobilizing sulfur/lithium polysulfides in cathodes, and accommodating the volume changes in sulfur-based cathodes. Therefore, the rational design of sulfur-containing composites needs to be emphasized as key strategies to develop high-performance cathodes for Li-S batteries. In this perspective, after reviewing the achievements obtained in the design of sulfur-containing composites as cathodes for Li-S batteries, we propose the new issues that should be overcome to facilitate the practical application of Li-S batteries. 

Place, publisher, year, edition, pages
AMER INST PHYSICS, 2019
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:umu:diva-157534 (URN)10.1063/1.5081915 (DOI)000460030300004 ()
Available from: 2019-04-01 Created: 2019-04-01 Last updated: 2019-04-01Bibliographically approved
Iakunkov, A., Sun, J., Rebrikova, A., Korobov, M., Klechikov, A., Vorobiev, A., . . . Talyzin, A. V. (2019). Swelling of graphene oxide membranes in alcohols: effects of molecule size and air ageing.. Journal of Materials Chemistry A, 7, 11331-11337
Open this publication in new window or tab >>Swelling of graphene oxide membranes in alcohols: effects of molecule size and air ageing.
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2019 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 7, p. 11331-11337Article in journal (Refereed) Published
Abstract [en]

Swelling of Hummers graphene oxide (HGO) membranes in a set of progressively longer liquid alcohols (methanol to 1-nonanol) was studied using synchrotron radiation XRD after air ageing over prolonged periods of time. Both precursor graphite oxides and freshly prepared HGO membranes were found to swell in the whole set of nine liquid alcohols with an increase of interlayer spacing from ∼7 Å (solvent free) up to ∼26 Å (in 1-nonanol). A pronounced effect of ageing on swelling in alcohols was found for HGO membranes stored in air. The HGO membranes aged for 0.5–1.5 years show progressively slower swelling kinetics, a non-monotonic decrease of saturated swelling in some alcohols and complete disappearance of swelling for alcohol molecules larger than hexanol. Moreover, the HGO membranes stored under ambient conditions for 5 years showed a nearly complete absence of swelling in all alcohols but preserved swelling in water. In contrast, precursor graphite oxide powder showed unmodified swelling in alcohols even after 4 years of ageing. Since the swelling defines the size of permeation channels, the ageing effect is one of the important parameters which could explain the strong variation in reported filtration/separation properties of GO membranes. The time and conditions of air storage require standardization for better reproducibility of results related to performance of GO membranes in various applications. The ageing of GO membranes can be considered not only as a hindrance/degradation for certain applications, but also as a method to tune the swelling properties of HGO membranes for better selectivity in sorption of solvents and for achieving better selective permeability.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2019
National Category
Materials Chemistry
Research subject
Physics
Identifiers
urn:nbn:se:umu:diva-160413 (URN)10.1039/C9TA01902B (DOI)000472225200050 ()
Funder
EU, Horizon 2020, 785219The Kempe Foundations
Available from: 2019-06-18 Created: 2019-06-18 Last updated: 2019-07-18Bibliographically approved
Sun, J., Klechikov, A., Moise, C., Prodana, M., Enachescu, M. & Talyzin, A. (2018). A Molecular Pillar Approach To Grow Vertical Covalent Organic Framework Nanosheets on Graphene: Hybrid Materials for Energy Storage. Angewandte Chemie International Edition, 57(4), 1034-1038
Open this publication in new window or tab >>A Molecular Pillar Approach To Grow Vertical Covalent Organic Framework Nanosheets on Graphene: Hybrid Materials for Energy Storage
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2018 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 57, no 4, p. 1034-1038Article in journal (Refereed) Published
Abstract [en]

Hybrid 2D–2D materials composed of perpendicularly oriented covalent organic frameworks (COFs) and graphene were prepared and tested for energy storage applications. Diboronic acid molecules covalently attached to graphene oxide (GO) were used as nucleation sites for directing vertical growth of COF-1 nanosheets (v-COF-GO). The hybrid material has a forest of COF-1 nanosheets with a thickness of 3 to 15 nm in edge-on orientation relative to GO. The reaction performed without molecular pillars resulted in uncontrollable growth of thick COF-1 platelets parallel to the surface of GO. The v-COF-GO was converted into a conductive carbon material preserving the nanostructure of precursor with ultrathin porous carbon nanosheets grafted to graphene in edge-on orientation. It was demonstrated as a high-performance electrode material for supercapacitors. The molecular pillar approach can be used for preparation of many other 2D-2D materials with control of their relative orientation.

Place, publisher, year, edition, pages
John Wiley & Sons, 2018
National Category
Condensed Matter Physics
Research subject
nanomaterials
Identifiers
urn:nbn:se:umu:diva-145739 (URN)10.1002/anie.201710502 (DOI)000428208700030 ()29210484 (PubMedID)
Available from: 2018-03-16 Created: 2018-03-16 Last updated: 2018-06-09Bibliographically approved
Klechikov, A., You, S., Lackner, L., Sun, J., Iakunkov, A., Rebrikova, A., . . . Talyzin, A. V. (2018). Graphite oxide swelling in molten sugar alcohols and their aqueous solutions. Carbon, 140, 157-163
Open this publication in new window or tab >>Graphite oxide swelling in molten sugar alcohols and their aqueous solutions
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2018 (English)In: Carbon, ISSN 0008-6223, E-ISSN 1873-3891, Vol. 140, p. 157-163Article in journal (Refereed) Published
Abstract [en]

Graphite oxides (GO) are intercalated rapidly by one to several layers of solvent when immersed in liquid but the GO solvates are typically unstable on air due to solvent evaporation. Here we study swelling of GO in solvents (sugar alcohols) with melting temperature point above ambient. Using in situ synchrotron radiation XRD experiments we demonstrated GO swelling in molten xylitol and sorbitol. The expanded GO structure intercalated with one layer of xylitol or sorbitol is preserved upon solidification of melt and cooling back to ambient conditions. The structure of solid solvates of GO with xylitol and sorbitol is based on non-covalent interaction and pristine GO can be recovered by washing in water. Intercalation of xylitol and sorbitol into GO structure in aqueous solutions yields similar but less ordered structure of GO/sugar alcohol solid solvates. Very similar inter-layer distance was observed for GO intercalated by sugar alcohols in melt and for GO immersed in sugar solutions. This result shows that sugar alcohols penetrate into GO inter-layer space without hydration shell forming 2D layers with orientation parallel to graphene oxide sheets. Therefore, hydration diameter of molecules should not be considered as decisive factor for permeation through graphene oxide inter-layers in multilayered membranes.

Place, publisher, year, edition, pages
Elsevier, 2018
Keywords
graphene, graphene oxide, swelling
National Category
Physical Chemistry
Identifiers
urn:nbn:se:umu:diva-151276 (URN)10.1016/j.carbon.2018.08.033 (DOI)000450120200016 ()
Funder
EU, Horizon 2020Swedish Research CouncilÅForsk (Ångpanneföreningen's Foundation for Research and Development)The Kempe Foundations
Available from: 2018-08-31 Created: 2018-08-31 Last updated: 2018-12-20Bibliographically approved
Iakunkov, A., Klechikov, A., Sun, J., Steenhaut, T., Hermans, S., Filinchuk, Y. & Talyzin, A. (2018). Gravimetric tank method to evaluate material-enhanced hydrogen storage by physisorbing materials. Physical Chemistry, Chemical Physics - PCCP, 20(44), 27983-27991
Open this publication in new window or tab >>Gravimetric tank method to evaluate material-enhanced hydrogen storage by physisorbing materials
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2018 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 20, no 44, p. 27983-27991Article in journal (Refereed) Published
Abstract [en]

The most common methods to evaluate hydrogen sorption (volumetric and gravimetric) require significant experience and expensive equipment for providing reproducible results. Both methods allow one to measure excess uptake values which are used to calculate the total amount of hydrogen stored inside of a tank as required for applications. Here we propose an easy to use and inexpensive alternative approach which allows one to evaluate directly the weight of hydrogen inside a material-filled test tank. The weight of the same tank filled with compressed hydrogen in the absence of loaded material is used as a reference. We argue that the only parameter which is of importance for hydrogen storage applications is by how much the material improves the total weight of hydrogen inside of the given volume compared to compressed gas. This parameter which we propose to name Gain includes both volumetric and gravimetric characterization of the material; it can be determined directly without knowing the skeletal volume of the material or excess sorption. The feasibility of the Gravimetric Tank (GT) method was tested using several common carbon and Metal Organic Framework (MOF) materials. The best Gain value of ∼12% was found for the Cu-BTC MOF which means that the tank completely filled with this material stores a 12% higher amount of hydrogen compared to H2 gas at the same PTconditions. The advantages of the GT method are its inexpensive design, extremely simple procedures and direct results in terms of tank capacity as required for industrial applications. The GT method could be proposed as a standard check for verification of the high hydrogen storage capacity of new materials. The GT method is expected to provide even better accuracy for evaluation of a material's performance for storage of denser gases like e.g. CO2 and CH4.

National Category
Physical Chemistry
Identifiers
urn:nbn:se:umu:diva-154041 (URN)10.1039/c8cp05241g (DOI)000450660400026 ()30382273 (PubMedID)
Funder
EU, Horizon 2020, 696656EU, Horizon 2020, N785219The Kempe FoundationsSwedish Research Council, 2017-04173
Available from: 2018-12-19 Created: 2018-12-19 Last updated: 2018-12-19Bibliographically approved
Klechikov, A., Sun, J., Vorobiev, A. & Talyzin, A. V. (2018). Swelling of Thin Graphene Oxide Films Studied by in Situ Neutron Reflectivity. The Journal of Physical Chemistry C, 122(24), 13106-13116
Open this publication in new window or tab >>Swelling of Thin Graphene Oxide Films Studied by in Situ Neutron Reflectivity
2018 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 122, no 24, p. 13106-13116Article in journal (Refereed) Published
Abstract [en]

Permeation of multilayered graphene oxide (GO) membranes by polar solvents is known to correlate with their swelling properties and amount of sorbed solvent. However, quantitative estimation of sorption using standard (e.g., gravimetric) methods is technically challenging for few nanometers thick GO membranes/films exposed to solvent vapors. Neutron reflectivity (NR) was used here to evaluate the amount of solvents intercalated into the film which consists of only ∼31.5 layers of GO. Analysis of NR data recorded from the GO film exposed to vapors of polar solvents provides information about change of film thickness due to swelling, amount of intercalated solvent, and selectivity in sorption of solvents from binary mixtures. A quantitative study of GO film sorption was performed for D2O, d-methanol, ethanol, dimethyl sulfoxide (DMSO), acetonitrile, dimethylformamide (DMF), and acetone. Using isotopic contrast, we estimated selectivity in sorption of ethanol/d-methanol mixtures by the GO film. Estimation of sorption selectivity was also performed for D2O/DMF, D2O/DMSO, and D2O/acetonitrile binary mixtures. Sorption of polar solvents was compared for the thin GO film, micrometer thick free standing GO membranes, and graphite oxide powders.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2018
Keywords
graphene, graphene oxide, swelling
National Category
Physical Chemistry
Research subject
Physics
Identifiers
urn:nbn:se:umu:diva-151273 (URN)10.1021/acs.jpcc.8b01616 (DOI)000436381600057 ()2-s2.0-85047617225 (Scopus ID)
Funder
EU, Horizon 2020
Available from: 2018-08-31 Created: 2018-08-31 Last updated: 2018-10-31Bibliographically approved
Klechikov, A., Sun, J., Hu, G., Zheng, M., Wågberg, T. & Talyzin, A. V. (2017). Graphene decorated with metal nanoparticles: Hydrogen sorption and related artefacts. Microporous and Mesoporous Materials, 250, 27-34
Open this publication in new window or tab >>Graphene decorated with metal nanoparticles: Hydrogen sorption and related artefacts
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2017 (English)In: Microporous and Mesoporous Materials, ISSN 1387-1811, E-ISSN 1873-3093, Vol. 250, p. 27-34Article in journal (Refereed) Published
Abstract [en]

Hydrogen sorption by reduced graphene oxides (r-GO) is not found to increase after decoration with Pd and Pt nanoparticles. Treatments of metal decorated samples using annealing under hydrogen or air were tested as a method to create additional pores by effects of r-GO etching around nanoparticles. Increase of Specific Surface Area (SSA) was observed for some air annealed r-GO samples. However, the same treatments applied to activated r-GO samples with microporous nature and higher surface area result in breakup of structure and dramatic decrease of SSA. Our experiments have not revealed effects which could be attributed to spillover in hydrogen sorption on Pd or Pt decorated graphene. However, we report irreversible chemisorption of hydrogen for some samples which can be mistakenly assigned to spillover if the experiments are incomplete.

Keywords
Graphene, Hydrogen storage, Graphene oxide, Nanoparticles, Decoration
National Category
Materials Chemistry
Identifiers
urn:nbn:se:umu:diva-135589 (URN)10.1016/j.micromeso.2017.05.014 (DOI)000405045800004 ()
Funder
EU, Horizon 2020
Available from: 2017-05-31 Created: 2017-05-31 Last updated: 2018-06-09Bibliographically approved
Klechikov, A., Sun, J., Baburin, I. A., Seifert, G., Rebrikova, A. T., Avramenko, N. V., . . . Talyzin, A. V. (2017). Multilayered intercalation of 1-octanol into Brodie graphite oxide. Nanoscale, 9(20), 6929-6936
Open this publication in new window or tab >>Multilayered intercalation of 1-octanol into Brodie graphite oxide
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2017 (English)In: Nanoscale, ISSN 2040-3364, E-ISSN 2040-3372, Vol. 9, no 20, p. 6929-6936Article in journal (Refereed) Published
Abstract [en]

Multilayered intercalation of 1-octanol into the structure of Brodie graphite oxide (B-GO) was studied as a function of temperature and pressure. Reversible phase transition with the addition/removal of one layer of 1-octanol was found at 265 K by means of X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC). The same transition was observed at ambient temperature upon a pressure increase above 0.6 GPa. This transition was interpreted as an incongruent melting of the low temperature/high pressure B-GO intercalated structure with five layers of 1-octanol parallel to GO sheets (L-solvate), resulting in the formation of a four-layered structure that is stable under ambient conditions (A-solvate). Vacuum heating allows the removal of 1-octanol from the A-solvate layer by layer, while distinct sets of (00 l) reflections are observed for three-, two-, and one-layered solvate phases. Step by step removal of the 1-octanol layers results in changes of distance between graphene oxide planes by similar to 4.5 angstrom. This experiment proved that both L- and A-solvates are structures with layers of 1-octanol parallel to GO planes. Unusual intercalation with up to five distinct layers of 1-octanol is remarkably different from the behaviour of small alcohol molecules (methanol and ethanol), which intercalate B-GO structure with only one layer under ambient conditions and a maximum of two layers at lower temperatures or higher pressures. The data presented in this study make it possible to rule out a change in the orientation of alcohol molecules from parallel to perpendicular to the GO planes, as suggested in the 1960s to explain larger expansion of the GO lattice due to swelling with larger alcohols.

National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:umu:diva-136327 (URN)10.1039/c7nr01792h (DOI)000402034400038 ()28509924 (PubMedID)
Funder
EU, Horizon 2020, 696656
Available from: 2017-06-30 Created: 2017-06-30 Last updated: 2018-06-09Bibliographically approved
Sun, J., Morales-Lara, F., Klechikov, A., Talyzin, A. V., Baburin, I. A., Seifert, G., . . . Giordani, S. (2017). Porous graphite oxide pillared with tetrapod-shaped molecules. Carbon, 120, 145-156
Open this publication in new window or tab >>Porous graphite oxide pillared with tetrapod-shaped molecules
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2017 (English)In: Carbon, ISSN 0008-6223, E-ISSN 1873-3891, Vol. 120, p. 145-156Article in journal (Refereed) Published
Abstract [en]

Porous pillared graphene oxide (GO) materials were prepared using solvothermal reaction of Hummers GO with solution of Tetrakis(4-aminophenyl)methane (TKAm) in methanol. The intercalation of TKAm molecules between individual GO sheets, performed under swelling condition, results in expansion of inter-layer distance of GO from ∼7.5 Å to 13-14 Å. Pillaring GO with bulky, rigid 3D shaped TKAm molecules could be an advantage for the preparation of stable pillared structures compared to e.g. aliphatic or aromatic diamines. Insertion of TKAm molecules into inter-layer space of GO results in formation of interconnected network of sub-nanometer slit pores. The expanded GO structure prepared with optimized GO/TKAm composition shows Specific Surface Area (SSA) up to 660 m2/g which is among the highest reported for GO materials pillared using organic spacers. Modelling of GO structures pillared with TKAm molecules shows that maximal SSA of about 2300 m2/g is theoretically possible for realistic concentration of pillaring molecules in GO interlayers. Hydrogen sorption by pillared GO/TKAm is found to follow standard correlation with SSA both at ambient and liquid nitrogen temperatures with highest uptakes of 1.66 wt% achieved at 77 K and 0.25 wt% at 295 K. Our theoretical simulations show that pillared GO structures do not provide improvement of hydrogen storage beyond well-established physisorption trends even for idealized materials with subnanometer pores and SSA of 2300–3700 m2/g.

Place, publisher, year, edition, pages
Elsevier, 2017
National Category
Physical Chemistry Condensed Matter Physics
Identifiers
urn:nbn:se:umu:diva-137608 (URN)10.1016/j.carbon.2017.05.007 (DOI)000403665000019 ()
Available from: 2017-07-10 Created: 2017-07-10 Last updated: 2018-06-09Bibliographically approved
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