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Effect of acceptor strength on optical, electrochemical and photovoltaic properties of phenothiazine-based small molecule for bulk heterojunction organic solar cells
Umeå universitet, Teknisk-naturvetenskapliga fakulteten, Kemiska institutionen.
Umeå universitet, Teknisk-naturvetenskapliga fakulteten, Kemiska institutionen.
2018 (engelsk)Inngår i: Dyes and pigments, ISSN 0143-7208, E-ISSN 1873-3743, Vol. 149, s. 830-842Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Two new acceptor–π(donor)–donor–π(donor)-acceptor small molecules SM1 and SM2 with benzodithiophene (BDT) donor core unit linked via phenothiazine (PTZ) donor units with 1,3–indanedione and malononitrile end capping units, respectively, have been designed and synthesized and used as electron donor along with PC71BM as acceptor for solution-processed bulk heterojunction organic solar cells. The influence of these end-capping groups on their thermal, optical, electrochemical properties and photovoltaic performance was investigated. After the optimization of the donor to acceptor weight ratio and solvent vapor annealing, the organic solar cells based on SM1:PC71BM and SM2:PC71BM active layers showed the power conversion efficiency (PCE) of 6.20% and 7.45%, respectively. Hence, the end-capping acceptor units for the two small molecules revealed a significant influence on the PCE of the organic solar cells, which resulted from differences in film absorption, molecular packing and charge transport properties.

sted, utgiver, år, opplag, sider
Elsevier, 2018. Vol. 149, s. 830-842
Emneord [en]
Small molecule donors, Bulk heterojunction solar cells, Solvent vapor annealing, Power conversion efficiency
HSV kategori
Identifikatorer
URN: urn:nbn:se:umu:diva-143018DOI: 10.1016/j.dyepig.2017.11.048ISI: 000423246900101OAI: oai:DiVA.org:umu-143018DiVA, id: diva2:1166173
Tilgjengelig fra: 2017-12-14 Laget: 2017-12-14 Sist oppdatert: 2018-06-09bibliografisk kontrollert
Inngår i avhandling
1. Molecular design, synthesis and performance evaluation of phenothiazine-based small molecules for efficient organic solar cells
Åpne denne publikasjonen i ny fane eller vindu >>Molecular design, synthesis and performance evaluation of phenothiazine-based small molecules for efficient organic solar cells
2018 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Alternativ tittel[sv]
Design, syntes och utvärdering av fenotiazin-innehållande små molekyler till effektiva organiska solceller
Abstract [en]

Photovoltaics offers one of the most promising routes to generate electricity in a clean way. As an emerging technology in photovoltaics, organic solar cells (OSC) have attracted a great deal of attention owing to their potential low-cost, lightweight, flexibility and solution processability. Although power conversion efficiencies above 12% have been achieved at this date, there is a great interest for new ideal materials to further improve the PCEs and address device durability, which are major concerns for the commercialization of this technology. The main objective of this thesis is to design and synthesize phenothiazine-based conjugate small molecules and explore their use as electron donor components in OSCs. Phenothiazine is a non-planar moiety with unusual “butterfly” type of geometry, which is known to reduce molecular aggregation and intermolecular excimer formation.

In the first study of this thesis, a small molecule based on a cyano-arylenevinylene building block with deep HOMO level was prepared. Although a high open-circuit voltage of 1.0 V was achieved, the tendency of the small molecule to crystallize in the active layer at a higher temperature and with time hindered the attainment of an optimal phase morphology required for the achievement of a higher efficiency. In the second and third studies, phenothiazine was used as a π-system bridge and as a core unit to construct small molecules based on symmetric and asymmetric frameworks with varying terminal electron-withdrawing groups. The electron-withdrawing property of the terminal units was found to have a significant influence on the optical absorption properties, electronic energy levels, molecular ordering, charge carrier mobility and morphology of the resulting active layers. In the fourth study, side-chain modification of the phenothiazine unit of symmetrically configured small molecules with an oxygen-containing (methoxyethoxy ethyl) side chain resulted in the enhancement of the dielectric constant. Although absorption properties were unchanged in solution, a dense π-π stacking was observed in the solid state.

In summary, it is demonstrated that phenothiazine is a promising candidate and worth exploring donor material for OSCs. Its versatility as a π-linker and as a central core unit in symmetric and asymmetric configurations has been explored. The use of nonplanar building blocks such as phenothiazine for the construction of donor materials is an interesting strategy for controlling molecular aggregation and difficult solution processability of small molecules if it is combined with a judiciously designed conjugate backbone.

sted, utgiver, år, opplag, sider
Umeå: Umeå University, 2018. s. 90
Emneord
Organic solar cell, small molecule donors, phenothiazine, power conversion efficiency
HSV kategori
Forskningsprogram
organisk kemi
Identifikatorer
urn:nbn:se:umu:diva-144465 (URN)978-91-7601-835-4 (ISBN)
Disputas
2018-02-28, KBE301 - Lilla Hörsalen, KBC-huset, Umeå, 10:00 (engelsk)
Opponent
Veileder
Tilgjengelig fra: 2018-02-07 Laget: 2018-02-04 Sist oppdatert: 2018-06-09bibliografisk kontrollert

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