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Ozonolysis of monoterpenes in mechanical ventilation systems
Umeå universitet, Teknisk-naturvetenskaplig fakultet, Kemi.
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2005 (Engelska)Ingår i: ATMOSPHERIC ENVIRONMENT, Vol. 39, nr 34, s. 6315-25Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

In this investigation the ozonolysis of of three monoterpenes (alpha-pinene, Delta(3)-carene and limonene) was studied was studied in authentic mechanical ventilation systems, that included either a cross flow or a rotary heat exchanger. The effects of varying three experimental parameters were investigated: the level of ozone (25 and 75 ppb), the reaction time (25 and 75s), and the surface area in the ventilation duct (14.8 and 29.5 m(2)). The initial concentration of each of the monoterpenes was 20 ppb in every experiment, and 1-16% of the alpha-pinene, < 0.5-13% of the Delta(3)-carene, and < 0.5-16% of the limonene reacted. The effects of humidity (g m(-3)) and temperature of the outdoor and supply air, and water losses in the ventilation duct, were also evaluated. Experiments were based on a chemometric statistical design. Comparison of the results to theoretically calculated values showed that theoretical calculations underestimated the amounts that reacted in the ventilation systems by factors of 2-13, depending on the monoterpene and experimental settings.

Ort, förlag, år, upplaga, sidor
2005. Vol. 39, nr 34, s. 6315-25
Nyckelord [en]
relative humidity, surface chemistry, heat exchanger, ventilation duct
Identifikatorer
URN: urn:nbn:se:umu:diva-13375DOI: doi:10.1016/j.atmosenv.2005.07.013OAI: oai:DiVA.org:umu-13375DiVA, id: diva2:153046
Tillgänglig från: 2007-05-08 Skapad: 2007-05-08 Senast uppdaterad: 2018-06-09Bibliografiskt granskad

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Fick, JerkerPommer, LindaÅstrand, AndersÖstin, RonnyAndersson, Barbro

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