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Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe-2(mμ-SCHR2)(2)(NO)(4)], R = Me, Ph
Russia.
Russia.
Russia.
Umeå universitet, Teknisk-naturvetenskapliga fakulteten, Kemiska institutionen.
Vise andre og tillknytning
2015 (engelsk)Inngår i: Polyhedron, ISSN 0277-5387, E-ISSN 1873-3719, Vol. 90, s. 197-201Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

New dinitrosyl iron complexes of binuclear structure [Fe-2(mu-SCHMe2)(2)(NO)(4)] and [Fe-2(mu-SCHPh2)(2)(NO)(4)] were first synthesized employing new method from Fe(CO)(5), corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied.

sted, utgiver, år, opplag, sider
Elsevier, 2015. Vol. 90, s. 197-201
Emneord [en]
Crystal structure, Thiolate ligands, Dinitrosyl iron complex, Nitric oxide donor, DFT calculations
HSV kategori
Identifikatorer
URN: urn:nbn:se:umu:diva-103142DOI: 10.1016/j.poly.2015.02.009ISI: 000352663900026OAI: oai:DiVA.org:umu-103142DiVA, id: diva2:813392
Tilgjengelig fra: 2015-05-22 Laget: 2015-05-18 Sist oppdatert: 2018-06-07bibliografisk kontrollert

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