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Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids
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2007 (English)In: Applied organometallic chemistry, ISSN 0268-2605, E-ISSN 1099-0739, Vol. 21, no 3, p. 156-160Article in journal (Refereed) Published
Abstract [en]

Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using Pd-C, Pd(OAc)(2) and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF4], chlorobenzene was dehalogenated by up to 40%, bromobenzene up to 25% and iodobenzene up to 41% in 2 h. Reactions in the absence of the ionic liquid were also performed.

Place, publisher, year, edition, pages
2007. Vol. 21, no 3, p. 156-160
Keyword [en]
dehalogenation, ionic liquids, molten salts, haloaromatics, palladium
National Category
Organic Chemistry Other Chemistry Topics
Identifiers
URN: urn:nbn:se:umu:diva-129154DOI: 10.1002/aoc.1194ISI: 000244659300006OAI: oai:DiVA.org:umu-129154DiVA, id: diva2:1058411
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2018-06-09Bibliographically approved

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Ohlin, C. André

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