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Oxygen isotopic exchange in an (MnMn3IV)-Mn-III-oxo cubane
2009 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, no 27, p. 5278-5280Article in journal (Refereed) Published
Abstract [en]

The rate and activation parameters for oxygen exchange of the mu(3)-oxo bridges in a manganese tetranuclear cluster with (H2O)-O-18 have been measured by ESI-MS; the observed Delta S double dagger of -146 +/- 22 J K-1 mol(-1) is consistent with the expected associative mechanism of substitution.

Place, publisher, year, edition, pages
2009. no 27, p. 5278-5280
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Inorganic Chemistry Physical Chemistry
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URN: urn:nbn:se:umu:diva-129148DOI: 10.1039/b906169jISI: 000267571600003PubMedID: 19565077OAI: oai:DiVA.org:umu-129148DiVA, id: diva2:1058585
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2018-06-09Bibliographically approved

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Ohlin, C. Andre

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