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Coordination Induced Atropisomerism in an NHC-Based Rhodium Macrocycle
2015 (English)In: Organometallics, ISSN 0276-7333, E-ISSN 1520-6041, Vol. 34, no 5, 913-917 p.Article in journal (Refereed) Published
Abstract [en]

Reversible interaction with carbon monoxide results in the onset of dynamic atropisomerism at 298 K in an otherwise static NHC-based rhodium pincer complex, [Rh(C boolean AND N boolean AND C-(CH2)(12))(CO)][BArF4] (1, ArF = 3,5-C6H3(CF3)(2)). The mechanism of this process has been comprehensively interrogated by a combination of variable-temperature NMR spectroscopy, IR spectroscopy, and computational modeling. In addition, a structural analogue of a high-energy symmetrical intermediate species-invoked in the process but not directly observed spectroscopically-has been prepared and characterized in solution and the solid-state.

Place, publisher, year, edition, pages
2015. Vol. 34, no 5, 913-917 p.
National Category
Inorganic Chemistry Theoretical Chemistry Physical Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-129108DOI: 10.1021/om501292kISI: 000350841200013OAI: oai:DiVA.org:umu-129108DiVA: diva2:1058611
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2017-02-08Bibliographically approved

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Ohlin, C. Andre
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