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Solvent promoted reversible cyclometalation in a tethered NHC iridium complex
2014 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, no 6, 685-687 p.Article in journal (Refereed) Published
Abstract [en]

Reaction of [Ir(COD)(py-(IBu)-Bu-t)](+) (py-(IBu)-Bu-t = 3-tert-butyl-1-picolylimidazol-2-ylidene) with acetonitrile results in reversible intramolecular C-H bond activation of the NHC ligand and formation of [Ir(g(2):g 1-C8H13)(py-ItBu’)(NCMe)](+). Coordinated COD acts as an internal hydride acceptor and acetonitrile coordination offsets the otherwise unfavourable thermodynamics of the process.

Place, publisher, year, edition, pages
2014. Vol. 50, no 6, 685-687 p.
National Category
Theoretical Chemistry Inorganic Chemistry Physical Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-129116DOI: 10.1039/c3cc48015aOAI: oai:DiVA.org:umu-129116DiVA: diva2:1058628
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2016-12-21

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Ohlin, C. Andre
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