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Solvent promoted reversible cyclometalation in a tethered NHC iridium complex
2014 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, no 6, p. 685-687Article in journal (Refereed) Published
Abstract [en]

Reaction of [Ir(COD)(py-(IBu)-Bu-t)](+) (py-(IBu)-Bu-t = 3-tert-butyl-1-picolylimidazol-2-ylidene) with acetonitrile results in reversible intramolecular C-H bond activation of the NHC ligand and formation of [Ir(g(2):g 1-C8H13)(py-ItBu’)(NCMe)](+). Coordinated COD acts as an internal hydride acceptor and acetonitrile coordination offsets the otherwise unfavourable thermodynamics of the process.

Place, publisher, year, edition, pages
2014. Vol. 50, no 6, p. 685-687
National Category
Theoretical Chemistry Inorganic Chemistry Physical Chemistry
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URN: urn:nbn:se:umu:diva-129116DOI: 10.1039/c3cc48015aOAI: oai:DiVA.org:umu-129116DiVA, id: diva2:1058628
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2018-06-09

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Ohlin, C. Andre

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