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Reaction Dynamics and Solution Chemistry of Polyoxometalates by Electrospray Ionization Mass Spectrometry
2012 (English)In: Chemistry - An Asian Journal, ISSN 1861-4728, E-ISSN 1861-471X, Vol. 7, no 2, 262-270 p.Article in journal (Refereed) Published
Abstract [en]

Mass spectrometry both complements other analytical techniques and allows for types of analyses and experiments not possible with common analytical methods, such as NMR, IR, and UV/Vis spectroscopy. Electrospray constitutes one of the mildest forms of ionization, making it the preferred method for the analysis of large fragile or reactive ions. There is particular promise for mass spectrometry in aiding the characterization of polyoxometalates and their solutions, but caution must be taken in designing the experiments in order to yield reliable data and to avoid the temptation of over-interpreting the relevance of gas-phase data to solution chemistry.

Place, publisher, year, edition, pages
2012. Vol. 7, no 2, 262-270 p.
Keyword [en]
kinetics; mass spectrometry; polyoxometalates
National Category
Analytical Chemistry Inorganic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-129125DOI: 10.1002/asia.201100763OAI: oai:DiVA.org:umu-129125DiVA: diva2:1058653
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2016-12-21

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Ohlin, C. Andre
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