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A new class of soluble and stable transition-metal-substituted polyoxoniobate: [Cr-2(OH)(4)Nb10O30](8-)
2012 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 41, no 41, 12674-12677 p.Article in journal (Refereed) Published
Abstract [en]

Hydrothermal synthesis of [Cr-2(III)(OH)(4)Nb10O30](8-) in gram-scale quantities leads to a new polyoxometalate ion composed of two CrNb6O19 Lindqvist-type units that are fused via shared faces. The two Cr-III atoms are located in the centre of the molecule and are bridged by two mu(4)-O atoms. Electronic transitions are calculated using density functional theory and compare well with the measured UV-Vis spectra.

Place, publisher, year, edition, pages
2012. Vol. 41, no 41, 12674-12677 p.
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-129128DOI: 10.1039/c2dt31760eOAI: oai:DiVA.org:umu-129128DiVA: diva2:1058656
Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2016-12-21

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Ohlin, C. Andre
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