Non-Aqueous Microwave-Assisted Syntheses of Deca- and Hexa-Molybdovanadates
2017 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773Article in journal (Refereed) In press
We report a new approach for the synthesis of heterohexa- and heterodecametalates via the use of non-aqueous, microwave-assisted reaction conditions. The two novel molybdovanadates have been isolated and characterized in the solid and solution states using single-crystal X-ray diffraction, FT-IR, UV/Vis, multinuclear NMR spectroscopy, and ESI-MS. The relative stabilities of the possible structural isomers were probed using dispersion-corrected DFT calculations for both polyoxometalate systems.
Place, publisher, year, edition, pages
microwave chemistry, polyoxometalates, solution dynamics, spectroscopy, structural reorganization
IdentifiersURN: urn:nbn:se:umu:diva-132118DOI: 10.1002/anie.201608589OAI: oai:DiVA.org:umu-132118DiVA: diva2:1078530