High pressure infrared spectroscopy study on C60*CS2 solvates
2017 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 669, 49-53 p.Article in journal (Refereed) Published
High pressure IR study has been carried out on C-60*CS2 solvates up to 34.8 GPa. It is found that the intercalated CS2 molecules significantly affect the transformations of C-60 molecules under pressure. As a probe, the intercalated CS2 molecules can well detect the orientational ordering transition and deformation of C-60 molecules under pressure. The chemical stability of CS2 molecules under pressure is also dramatically enhanced due to the spacial shielding effet from C-60 molecules around in the solvated crystal. These results provide new insight into the effect of interactions between intercalants and fullerenes on the transformations in fullerene solvates under pressure.
Place, publisher, year, edition, pages
Elsevier, 2017. Vol. 669, 49-53 p.
High pressure, IR spectra, Fullerene, C-60*CS2 solvates
Physical Chemistry Atom and Molecular Physics and Optics
IdentifiersURN: urn:nbn:se:umu:diva-132131DOI: 10.1016/j.cplett.2016.11.047ISI: 000392774900008OAI: oai:DiVA.org:umu-132131DiVA: diva2:1080311