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Mild Reductive Functionalization of Amides into N-Sulfonylformamidines
Umeå University, Faculty of Science and Technology, Department of Chemistry. Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden.
2017 (English)In: ChemistryOpen, ISSN 2191-1363, Vol. 6, no 4, p. 484-487Article in journal (Refereed) Published
Abstract [en]

The development of a protocol for the reductive functionalization of amides into N-sulfonylformamidines is reported. The one-pot procedure is based on a mild catalytic reduction of tertiary amides into the corresponding enamines by the use of Mo(CO)(6) (molybdenum hexacarbonyl) and TMDS (1,1,3,3-tetramethyldisiloxane). The formed enamines were allowed to react with sulfonyl azides to give the target compounds in moderate to good yields.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2017. Vol. 6, no 4, p. 484-487
Keywords [en]
amides, amidines, enamines, reductive functionalization, sulfonyl azides
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-138585DOI: 10.1002/open.201700087ISI: 000407167100006OAI: oai:DiVA.org:umu-138585DiVA, id: diva2:1144146
Available from: 2017-09-25 Created: 2017-09-25 Last updated: 2018-06-09Bibliographically approved

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Adolfsson, Hans

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CiteExportLink to record
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Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
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  • de-DE
  • en-GB
  • en-US
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  • nn-NO
  • nn-NB
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  • Other locale
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Output format
  • html
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