umu.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Facile preparation of pyrimidinediones and thioacrylamides via reductive functionalization of amides
Umeå University, Faculty of Science and Technology, Department of Chemistry. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden.ORCID iD: 0000-0001-5887-4630
2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 65, 9159-9162 p.Article in journal (Refereed) Published
Abstract [en]

The development of an efficient protocol for the reductive function-alization of amides into pyrimidinediones and amino-substituted thioacrylamides is presented. Enamines are generated in a highly chemoselective amide hydrosilylation reaction catalyzed by molybdenum hexacarbonyl in combination with 1,1,3,3-tetramethyldisiloxane. The direct addition of either isocyanate or isothiocyanate generates the corresponding pyrimidinediones and 3-aminothioacryl-amides in high yields.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2017. Vol. 53, no 65, 9159-9162 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-138580DOI: 10.1039/c7cc04170eISI: 000407333400029OAI: oai:DiVA.org:umu-138580DiVA: diva2:1145607
Available from: 2017-09-29 Created: 2017-09-29 Last updated: 2017-09-29Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Adolfsson, Hans
By organisation
Department of Chemistry
In the same journal
Chemical Communications
Organic Chemistry

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 9 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf