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Synthesis and Spectroscopic Properties of Fluorinated Coumarin Lysine Derivatives
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2018 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 83, no 8, p. 4792-4799Article in journal (Refereed) Published
Abstract [en]

The site-selective incorporation of fluorescent amino acids into proteins has emerged as a valuable alternative to expressible protein reporters. For successful application, a robust and scalable, yet flexible, route to non-natural amino acids is required. This work describes an improved synthesis of coumarin-conjugated lysine derivatives where fluorinated variants are accessed. These analogues can be utilized at low pH and should find application probing biological processes that operate under acidic conditions.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2018. Vol. 83, no 8, p. 4792-4799
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-148028DOI: 10.1021/acs.joc.7b03214ISI: 000430898500046PubMedID: 29595263OAI: oai:DiVA.org:umu-148028DiVA, id: diva2:1211287
Available from: 2018-05-30 Created: 2018-05-30 Last updated: 2018-06-09Bibliographically approved

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Shukla, LakshmiMoodie, Lindon W. K.Kindahl, TomasHedberg, Christian

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