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An experimental investigation of large amplitude reversible square wave voltammetry
Umeå University, Faculty of Science and Technology, Chemistry.
Umeå University, Faculty of Science and Technology, Chemistry.
2002 (English)In: Journal of Electroanalytical Chemistry, Vol. 536, no 1, 161-9 p.Article in journal (Refereed) Published
Abstract [en]

Large amplitude square wave voltammetric experiments have been undertaken with model electrochemical system comprising aqueous solutions of tris(2,2'-bipyridine)osmium(II/III) and tris(2,2'-bipyridine)iron(II/III) redox couples, both of which exhibit reversible behaviour. Analysis of the current responses in the frequency domain were performed by means of Fourier transformation. Excellent agreement was obtained between the experimental voltammograms and those predicted by theory, both for single component solutions and for mixtures.

Place, publisher, year, edition, pages
2002. Vol. 536, no 1, 161-9 p.
Keyword [en]
Large-amplitude-square-wave voltammetry, Ac-voltammetry, Fourier transform
Identifiers
URN: urn:nbn:se:umu:diva-8565DOI: doi:10.1016/S0022-0728(02)00656-3OAI: oai:DiVA.org:umu-8565DiVA: diva2:148236
Available from: 2008-01-29 Created: 2008-01-29 Last updated: 2011-01-13Bibliographically approved

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Publisher's full texthttp://www.ingentaconnect.com/content/els/00220728/2002/00000536/00000001/art01222

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Sharp, Michael

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CiteExportLink to record
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