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Aqueous Peroxoisopolyoxometalates
Umeå University, Faculty of Science and Technology, Chemistry.
Umeå University, Faculty of Science and Technology, Chemistry.
2001 (English)In: Polyoxometalate Chemistry From Topology via Self-Assembly to Applications, 2001, 145-59 p.Chapter in book (Refereed)
Abstract [en]

New 17O NMR, potentiometry and ESI-MS measurements on aqueous peroxomolybdates and peroxotungstates reveal many new species, including diperoxo hepta-anions and also confirm other proposals based on potentiometry alone, such as a monoperoxo monomer. They also show the presence of many anions previously identified only in the solid state, including both forms of the Mo2(peroxide)4 anion. Comparison with recent work on peroxovanadates and peroxoniobates shows a marked preference in all cases for each metal atom to be coordinated to two peroxo ligands. Peroxotungstates, like tungstates themselves, are generally more complex than peroxovanadates and -molybdates.

Place, publisher, year, edition, pages
2001. 145-59 p.
Keyword [en]
17O NMR, peroxomolybdates, peroxotungstates, peroxovanadates, anion ESI-MS
URN: urn:nbn:se:umu:diva-9006DOI: doi:10.1007/0-306-47625-8_11ISBN: 978-0-7923-7011-6 (Print) 978-0-306-47625-9 (Online)OAI: diva2:148677
Available from: 2008-02-28 Created: 2008-02-28Bibliographically approved

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Pettersson, LageAndersson, Ingegärd
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