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Sodium trirubidium metavanadate monohydrate
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2003 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. E59, no 11, i151-i153 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, sodium trirubidium metavanadate monohydrate, NaRb3(VO3)4(H2O), crystallizes in the orthorhombic space group Pnma. The structure, which represents a rare type of catena-vanadate, is built up of strongly folded chains of corner-sharing [VO4] tetrahedra, running in the [010] direction with a periodicity of four. A three-dimensional framework is obtained by sodium ions linking adjacent chains in the [001] direction and by rubidium ions linking adjacent chains in the [100] direction. The single water molecule binds to the sodium ion and to two rubidium ions.

Place, publisher, year, edition, pages
International Union of Crystallography , 2003. Vol. E59, no 11, i151-i153 p.
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Chemical Sciences
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URN: urn:nbn:se:umu:diva-9281DOI: 10.1107/S1600536803024024OAI: oai:DiVA.org:umu-9281DiVA: diva2:148952
Available from: 2008-03-18 Created: 2008-03-18 Last updated: 2017-12-14Bibliographically approved

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Boström, DanPettersson, Lage
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