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Hexakis(dimethyl sulfoxide-KO)aluminium(III) trichloride
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2003 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 59, no 10, m934-m935 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, [Al{(CH3)2SO}6]Cl3, crystallizes in the trigonal space group R. In this structure, the O atoms of six dimethyl sulfoxide (DMSO) molecules are bonded to the Al3+ ion in the form of a trigonally distorted octahedron. The Al3+ ion is situated at special site 3b (symmetry ), while the Cl- ions are situated at special sites 3a and 6c (symmetries and 3). Considering only the Al3+ ions separately, they are arranged in a slightly distorted cubic close-packed arrangement. In this crystal structure, the Cl- ions occupy both the tetrahedral sites and the octahedral sites, giving a Cl-:Al3+ ratio of 3:1. This geometric condition results in a distorted rhombododecahedral arrangement of Cl- ions around the Al3+ ions.

Place, publisher, year, edition, pages
International Union of Crystallography , 2003. Vol. 59, no 10, m934-m935 p.
Identifiers
URN: urn:nbn:se:umu:diva-9285DOI: doi:10.1107/S1600536803020464OAI: oai:DiVA.org:umu-9285DiVA: diva2:148956
Available from: 2008-03-18 Created: 2008-03-18 Last updated: 2011-01-27Bibliographically approved

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Boström, Dan

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