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Tetraphenyl-and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands: Synthesis, X-ray diffraction analysis, and 13C and 15N CP/MAS NMR studies
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2006 (English)In: Russian Journal of Coordination Chemistry, Vol. 32:3, no 6, 87-396 p.Article in journal (Other (popular science, discussion, etc.)) Published
Abstract [en]

Crystalline tetraphenylantimony and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands [Sb(C6H5)4(S2CNR2)] (R = CH3, C2H5, and C3H7 and R2 = (CH2)6) were synthesized by ligand exchange reactions and studied by 13C and 15N CP/MAS NMR spectroscopy. X-ray diffraction analysis revealed that the complex [Sb(n-CH3-C6H4)4{S2CN(C3H7)2}] exists as the single molecular form, while [Sb(C6H5)4{S2CN(CH2)6}] exists as two molecular conformers. The 13C and 15N signals were assigned to the positions of the atoms in the isomeric structures [Sb(C6H5)4{S2CN(CH2)6}] in terms of different degrees of double bonding in the formally single =N-C(S)S-bond.

Place, publisher, year, edition, pages
2006. Vol. 32:3, no 6, 87-396 p.
URN: urn:nbn:se:umu:diva-12546DOI: doi:10.1134/S1070328406060017OAI: diva2:152217
Available from: 2007-04-11 Created: 2007-04-11 Last updated: 2011-01-11Bibliographically approved

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Gröbner, Gerhard
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Umeå University

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