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Microporous hydrophilic super-oxidized carbons with high surface area for removal of copper ions
Umeå University, Faculty of Science and Technology, Department of Physics.
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0000-0002-3881-6764
Center for Surface Science and Nanotechnology, National University of Science and Technology Politehnica Bucharest, Bucharest, Romania.
Center for Surface Science and Nanotechnology, National University of Science and Technology Politehnica Bucharest, Bucharest, Romania; Academy of Romanian Scientists, Bucharest, Romania.
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2024 (English)In: Microporous and Mesoporous Materials, ISSN 1387-1811, E-ISSN 1873-3093, Vol. 378, article id 113259Article in journal (Refereed) Published
Abstract [en]

Super-oxidized porous carbons produced from reduced graphene oxide have been demonstrated recently to show unique sorption properties. Here we report experiments with identical oxidative treatment applied to four very different types of porous carbon materials with extremely broad range of specific surface area (SSA) ∼350–3400 m2g−1. It is demonstrated that KOH-activated carbons can be oxidized to the same degree as graphene oxide (GO) while preserving a larger part of SSA. Prolonged oxidation with ammonium persulfate resulted in extraordinary high degree of oxidation with C/O ratio reaching 2.1. Precursor carbons with largest share of micropores are found to be more stable against oxidative treatment, while single-walled carbon nanotubes (SWCNT's) are oxidized to much less extent. While mesopores collapse, micropores survive strong oxidation treatment providing materials with rather narrow pore size distribution and high (for given oxidation degree) BET SSA up to ∼1150 m2g−1. Super-oxidized porous carbons (SOPC's) show a high abundance of hydroxyl, epoxide, carbonyl, and carboxyl functional groups (similar to GO). As a result of oxidation, the hydrophobic carbons are converted into hydrophilic materials. Characterization shows that many properties of SOPC (e.g. degree of oxidation, type of functional groups, thermal stability etc.) are rather similar to GO, except for three-dimensional porous structure which can be considered an advantage for sorbent applications. SOPC's demonstrate superior sorption capacity for Cu(II) (up to ∼105 mgg−1), which is 8-fold higher than the value for non-oxidized precursor.

Place, publisher, year, edition, pages
Elsevier, 2024. Vol. 378, article id 113259
Keywords [en]
Adsorbent, Chemical modification, Copper sorption, Porous carbon
National Category
Materials Chemistry Other Physics Topics
Identifiers
URN: urn:nbn:se:umu:diva-228131DOI: 10.1016/j.micromeso.2024.113259ISI: 001282466200001Scopus ID: 2-s2.0-85199429465OAI: oai:DiVA.org:umu-228131DiVA, id: diva2:1886845
Funder
Swedish Energy Agency, 50620-1ÅForsk (Ångpanneföreningen's Foundation for Research and Development), N 23-275The Kempe FoundationsAvailable from: 2024-08-05 Created: 2024-08-05 Last updated: 2025-04-24Bibliographically approved

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Gurzęda, BartoszBoulanger, NicolasTalyzin, Aleksandr V.

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