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Mesoporous carbon derived from lignin sulfonate as a sustainable cathode for high-performance aluminium batteries
School of Engineering Sciences and Technology, University of Hyderabad, Gachibowli, Telangana, Hyderabad, India; Biomass Technology Centre, Department of Forest Biomaterials and Technology, Swedish University of Agricultural Sciences, Umeå.
School of Engineering Sciences and Technology, University of Hyderabad, Gachibowli, Telangana, Hyderabad, India; Biomass Technology Centre, Department of Forest Biomaterials and Technology, Swedish University of Agricultural Sciences, Umeå.
Public Research University Engineering School, IMT Mines Albi, Albi, France.
Laboratory of Industrial Chemistry and Reaction Engineering, Faculty of Science and Engineering, Åbo Akademi University, Åbo/Turku, Finland; Biomass Technology Centre, Department of Forest Biomaterials and Technology, Swedish University of Agricultural Sciences, Umeå.
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2025 (English)In: Carbon Resources Conversion, E-ISSN 2588-9133, Vol. 8, no 1, article id 100301Article in journal (Refereed) Published
Abstract [en]

The development of sustainable and efficient energy storage systems is crucial for addressing the growing global energy demand. This study investigates the potential of mesoporous carbon derived from lignin sulfonate as a cathode material for aluminium batteries. Lignin sulfonate, a by-product of the paper industry, was used as a precursor to synthesize mesoporous carbon through a facile and eco-friendly activation process. The resulting carbon material exhibited a high specific surface area of ∼ 2259 m2/g and a well-defined balance of micro- and meso- porosity, making it a promising cathode material for high-performance aluminium batteries. Electrochemical characterization showed that the mesoporous carbon cathode delivered an impressive specific capacity of 91 mAh/g at 1.0 A/g current density even after 7000 cycles with excellent cycling stability. It delivered superior rate capabilities of 105, 89, 80, 72, 67, 63, 90, and 105 mAh/g at 0.1, 1.0, 2.0, 3.0, 4.0, 5.0, 1.0, and 0.1 A/g current rates, respectively. The use of lignin-sulfonate as a precursor to prepare mesoporous carbon opens up a new sustainable way for improving the electrochemical performance of carbon-based cathode materials for aluminium batteries.

Place, publisher, year, edition, pages
Elsevier, 2025. Vol. 8, no 1, article id 100301
Keywords [en]
Aluminium batteries, Cathode materials, Lignin sulfonate, Mesoporous carbon, Paper and pulp industry
National Category
Materials Chemistry Other Chemical Engineering
Identifiers
URN: urn:nbn:se:umu:diva-234152DOI: 10.1016/j.crcon.2024.100301ISI: 001427004400001Scopus ID: 2-s2.0-85214487314OAI: oai:DiVA.org:umu-234152DiVA, id: diva2:1930889
Funder
Bio4EnergyAcademy of Finland, 361583Available from: 2025-01-24 Created: 2025-01-24 Last updated: 2025-04-24Bibliographically approved

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Manavalan, Gopinathan

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