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Scotch pine cones-derived hard carbon as an anode material for sodium-ion battery applications
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0001-5984-752X
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0002-1705-5249
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0003-3927-6197
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0002-3973-0938
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2025 (English)In: ACS Omega, E-ISSN 2470-1343, Vol. 10, no 11, p. 11158-11167Article in journal (Refereed) Published
Abstract [en]

A biobased anode material for sodium-ion batteries (SIBs) was prepared through the simple pyrolysis of Scotch pine cones (Pinus sylvestris, SPC), followed by a heteroatom doping modification. The resulting nitrogen-doped hard carbon exhibited a high reversible capacity of 273 mA·h·g-1 at a current density of 25 mA·g-1 compared to the undoped material (197 mA·h·g-1). X-ray diffraction analysis shows that the produced hard carbon from the biomass is highly amorphous in nature, and high-resolution transmission electron microscopy images reveal the presence of localized graphite-like structures that are found to be beneficial for the storage and transport of Na+ ions during charging/discharging. Experimental results demonstrated that the increased specific surface area (SBET = 424 m2·g-1), high micropore volume (0.177 cm3·g-1), and expanded interlayer spacing (>3.7 Å) and a high Na+-ion diffusion coefficient (3.08 × 10-16 cm2·s-1) facilitated the diffusion of sodium ions, leading to a high capacity retention of 80% after 250 cycles for the SPC-N material over the undoped one, SPC (71%). This study highlights the potential of low-cost, widely available biobased Scotch pine cones as an alternative anode material to enhance the sustainability of SIB production.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2025. Vol. 10, no 11, p. 11158-11167
Keywords [en]
Anode materials, Batteries Electrical properties, Electrodes, Materials
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-237186DOI: 10.1021/acsomega.4c10363ISI: 001442068800001PubMedID: 40160790Scopus ID: 2-s2.0-105001086814OAI: oai:DiVA.org:umu-237186DiVA, id: diva2:1950749
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The Kempe Foundations, JCSMK22-0094Available from: 2025-04-09 Created: 2025-04-09 Last updated: 2025-04-28Bibliographically approved

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Rao, Y. BhaskaraSundman, OlaHolmboe, MichaelTavajohi Hassan Kiadeh, NaserOhlin, C. André

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