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Comparative Raman study of photopolymerised and pressure-polymerised C60 films
Umeå University, Faculty of Science and Technology, Physics.
Umeå University, Faculty of Science and Technology, Physics.
1999 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 60, no 7, 4535-4538 p.Article in journal (Refereed) Published
Abstract [en]

We have made a Raman study of low-pressure polymerized and photopolymerized C60 films, polymerized in different ways, but otherwise initially identical. Although the structures developing in the films during polymerization are initially very similar, an analysis of characteristic features in the Raman spectra shows that photopolymerized material forms a more complex polymeric structure when the polymerization approaches saturation. We suggest that this complex structure contains branched polymeric chains and in particular that a mode near 1454 cm-1 in photopolymerized C60 is characteristic for this type of structure.

Place, publisher, year, edition, pages
American Physical Society , 1999. Vol. 60, no 7, 4535-4538 p.
Keyword [en]
Fullerenes, C60, thin films, polymerization, high pressure synthesis, photo-polymerization, pressure polymerization, Raman spectroscopy, polymer chains
National Category
Condensed Matter Physics
Research subject
Physics
Identifiers
URN: urn:nbn:se:umu:diva-23221DOI: 10.1103/PhysRevB.60.4535OAI: oai:DiVA.org:umu-23221DiVA: diva2:222047
Available from: 2009-06-05 Created: 2009-06-05 Last updated: 2017-12-13

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Publisher's full texthttp://link.aps.org/doi/10.1103/PhysRevB.60.4535

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