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Pressure-induced modifications of structural and transport properties in SbCl5 intercalated graphite
Umeå University, Faculty of Science and Technology, Physics.
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1992 (English)In: Materials Science Forum volumes 91-93, Part I: Intercalation Compounds ISIC-6: Proceedings of the Sixth International Symposium on Intercalation Compounds, Orléans 1991., Zürich: Trans Tech Publications , 1992, 301-306 p.Conference paper, Published paper (Refereed)
Abstract [en]

The structure and the c-axis resistivity of SbCl5 intercalated graphite have been studied as functions of T and p, over the ranges 40 to 295 K and 0 to 0.7 GPa. Slow cooling or slow application of pressure p > 0.4 GPa lead to states of complete but different crystallization of the intercalate, but after rapid cooling or pressurization any crystallization is incomplete. The resistivity of the high pressure crystallized phase is about 50% lower than that of the low T, low p phase under identical p-T conditions. No significant difference is seen between the behaviour of HOPG-based and single crystal based materials.

Place, publisher, year, edition, pages
Zürich: Trans Tech Publications , 1992. 301-306 p.
Series
Materials Science Forum, ISSN 0255-5476 ; Volumes 91-93
Keyword [en]
Graphite Intercalation Compounds, GIC, SbCl5, high pressure, structure, resistivity, HOPG, single crystal graphite, in-plane crystallization, order-disorder transition
National Category
Condensed Matter Physics
Research subject
Physics
Identifiers
URN: urn:nbn:se:umu:diva-26570DOI: 10.4028/www.scientific.net/MSF.91-93.301ISBN: 0-87849-639-4 (print)OAI: oai:DiVA.org:umu-26570DiVA: diva2:272580
Note
Editors: D. Tchoubar and J. Conard. Conference proceedings published both in the journal (ISSN above) and as two volumes of conference proceedings (ISBN above).Available from: 2009-10-15 Created: 2009-10-15 Last updated: 2010-02-02

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