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Efficient, mild and completely regioselective synthesis of substituted pyridines
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Institutionen för kemi och molekylärbiologi, Göteborgs universitet, Göteborg, Sverige .
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2010 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 46, no 19, p. 3384-3386Article in journal (Refereed) Published
Abstract [en]

Addition of Grignard reagents to pyridine N-oxides in THF at low temperature (-78 to -20 °C) and treatment with TFAA provides an efficient general procedure for synthesis of substituted pyridines. The method is compatible with a range of functional groups such as esters, halogens and nitriles.

Place, publisher, year, edition, pages
RSC Publishing, 2010. Vol. 46, no 19, p. 3384-3386
Keywords [en]
Molecular Structure, Organometallic Compounds, chemistry, Pyridines, chemical synthesis, chemistry, Stereoisomerism, Temperature
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-32684DOI: 10.1039/c000748jISI: 000277318000047OAI: oai:DiVA.org:umu-32684DiVA, id: diva2:305100
Available from: 2010-03-22 Created: 2010-03-22 Last updated: 2018-06-08Bibliographically approved

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Almqvist, Fredrik

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