A new microscale method for the conversion of phosphorus oxyacids to their fluorinated analogues, using cyanuric fluoride in solution and on solid support
2010 (English)In: Phosphorus Sulfur and Silicon and the Related Elements, ISSN 1042-6507, E-ISSN 1563-5325, Vol. 185, no 12, 2402-2408 p.Article in journal (Refereed) Published
Cyanuric fluoride, in solution or loaded onto a Wang resin, is successfully used as a fluorinating agent for phosphorus oxy acids. The reaction is very efficient with high yields and easy workup procedures, thereby in general generating products in quantitative yields. The cyanuric fluoride is proven suitable for micromolar scale synthesis of analytical standards, particularly in its resin-bound form.
Place, publisher, year, edition, pages
Abingdon: Taylor & Francis, 2010. Vol. 185, no 12, 2402-2408 p.
Cyanuric fluoride, micro scale, phosphorus fluoridates, solid phase synthesis
IdentifiersURN: urn:nbn:se:umu:diva-32902DOI: 10.1080/10426501003671445ISI: 000284418300002OAI: oai:DiVA.org:umu-32902DiVA: diva2:306611
Rikard Norlin = Rikard Wärme2010-03-302010-03-302016-09-01Bibliographically approved