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Characterization of Hardwood-Derived Carboxymethylcellulose by High pH Anion Chromatography Using Pulsed Amperometric Detection
Åbo Akademi University, Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, FIN-20500 Turku/Åbo, Finland.
Umeå University, Faculty of Science and Technology, Department of Chemistry. (Laboratory of Technical Chemistry)
Åbo Akademi University, Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, FIN-20500 Turku/Åbo, Finland.
2010 (English)In: Cellulose Chemistry and Technology, ISSN 0576-9787, Vol. 44, no 1-3, 65-69 p.Article in journal (Refereed) Published
Abstract [en]

An approach for the quantitative analysis of substituent distribution in carboxymethylcellulose (CMC) is presented. In short, the high-pH anion-exchange chromatography method, coupled to pulsed amperometric detection (PAD), is introduced. Each of the seven derivatives in CMC is presented by a single peak on the PAD trace, thus enabling an easy quantification. New inside information on monomer composition is obtained by this novel method, which is essential for understanding the structure versus property relationships in the CMC samples.

Place, publisher, year, edition, pages
2010. Vol. 44, no 1-3, 65-69 p.
Keyword [en]
carboxymethyl cellulose, high-pH anion-exchange chromatography, substituent distribution
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:umu:diva-34396ISI: 000277683000010OAI: oai:DiVA.org:umu-34396DiVA: diva2:321242
Available from: 2010-05-31 Created: 2010-05-31 Last updated: 2015-10-12Bibliographically approved

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Mikkola, Jyri-Pekka

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CiteExportLink to record
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