umu.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Reaction products and transformations of intermediates in the aqueous-phase reforming of sorbitol
Show others and affiliations
2010 (English)In: ChemSusChem, ISSN 1864-564X, Vol. 3, no 6, 708-718 p.Article in journal (Refereed) Published
Abstract [en]

Aqueous phase reforming of sorbitol over Pt supported on an alumina catalyst is investigated, in order to identify the intermediates involved in the transformation of the initial feed. Parameters such as the sorbitol feed rate and temperature are studied. To identify the intermediates, an approach based on analysis of the gas and liquid phases as well as the total carbon content was developed. According to analysis by gas chromatography combined with mass spectrometry of volatile substances collected with solid-phase microextraction, over 260 compounds are involved in the transformation of sorbitol. Of these, 50 of the major products are identified with high reliability. It is shown that a great variety of compounds, bearing different functionalities, form part of the reaction network. The formation of the majority of identified compounds is explained and a reaction network for the formation of sorbitol and intermediate molecules transformation is proposed.

Place, publisher, year, edition, pages
Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA , 2010. Vol. 3, no 6, 708-718 p.
Keyword [en]
biofuels, heterogeneous catalysis, platinum, reaction mechanisms, renewable resources
Identifiers
URN: urn:nbn:se:umu:diva-34599DOI: 10.1002/cssc.200900254ISI: 000279753300013PubMedID: 20512804OAI: oai:DiVA.org:umu-34599DiVA: diva2:323075
Available from: 2010-06-09 Created: 2010-06-09 Last updated: 2010-08-10Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Mikkola, Jyri-Pekka
By organisation
Department of Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 89 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf