umu.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Multicomponent polyanions. 54. Crystal structure of tetracaesium monohydrogen phosphato(phosphito)pentamolybdate dihydrate, Cs-4[H(HP)PMo5O22]center dot 2H(2)O
1998 (English)In: Acta Chemica Scandinavica, ISSN 0904-213X, E-ISSN 1902-3103, Vol. 52, no 4, 425-430 p.Article in journal (Refereed) Published
Abstract [en]

The crystal structure of tetracaesium monohydrogen phosphato (phosphito)pentamolybdate dihydrate was determined by single-crystal X-ray diffraction. The compound crystallises in the triclinic space group P (1) over bar, a=10.284(2), b= 10.791(2) and c=13.047(3) Angstrom, alpha=109.34(2), beta=99.92(2) and gamma=102.85(2)degrees, V=1283.4(5) Angstrom(3) and Z=2. The final R-values are R=0.066, wR=0.039 and S=1.3667. The H(HP)PMo5O224- anion has common features with the Strandberg X2M5-type heteropolyanion. The five MoO6 octahedra form a five-membered ring by one corner-sharing and four edge-sharing connections, and the tripodal phosphate and phosphite ligands protrude from each side of this ring in opposite directions. This is the first example of the structure of the heteropolyoxometalate having both P-III and P-V as heteroatoms.

Place, publisher, year, edition, pages
1998. Vol. 52, no 4, 425-430 p.
Identifiers
URN: urn:nbn:se:umu:diva-38635ISI: 000072758500007OAI: oai:DiVA.org:umu-38635DiVA: diva2:379649
Available from: 2010-12-19 Created: 2010-12-19 Last updated: 2017-12-11

Open Access in DiVA

No full text

In the same journal
Acta Chemica Scandinavica

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 20 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf