Thermodynamic properties of dyscrasite (Ag3Sb) at isostatic pressures 4000-8000 bar
1998 (English)In: Physics and chemistry of minerals, ISSN 0342-1791, E-ISSN 1432-2021, Vol. 25, no 4, 288-291 p.Article in journal (Refereed) Published
The objective of the present study was to demonstrate the possibility of application of high-pressure equipment in combination with the solid state EMF technique. The equilibrium reaction 3 Ag+Sb double left right arrow Ag3Sb was chosen for the studies. The experiments were carried out under argon gas pressure and the majority of data points were measured in the pressure range 4000-8000 bar at temperatures 550-725 K. The solid electrolyte consisted of AgI. Reproducible results were obtained along seven isotherms and one isobar at 7100 bar. The molar volume change for the reaction studied was calculated and compared with corresponding literature data at one bar.
Place, publisher, year, edition, pages
1998. Vol. 25, no 4, 288-291 p.
IdentifiersURN: urn:nbn:se:umu:diva-38634ISI: 000072904500006OAI: oai:DiVA.org:umu-38634DiVA: diva2:379651