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Static Relative Dielectric Permittivities of Ionic Liquids at 25 °C
Department of Physical Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, D-44780 Bochum, Germany.
Department of Physical Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, D-44780 Bochum, Germany.
Department of Physical Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, D-44780 Bochum, Germany.
Department of Chemical Engineering, Laboratory of Analytical Chemistry, Åbo Akademi University.
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2011 (English)In: Journal of Chemical and Engineering Data, ISSN 0021-9568, E-ISSN 1520-5134, Vol. 56, no 4, 1494-1499 p.Article in journal (Refereed) Published
Abstract [en]

For understanding solvation by ionic liquids, it is mandatory to characterize their static relative dielectric permittivities ε (“static dielectric constants”). Exploiting the definition of ε in terms of the zero-frequency limit of the frequency-dependent dielectric dispersion curve, the static dielectric constant of an electrically conducting liquid can be extrapolated from dielectric relaxation spectra in the microwave regime. On the basis of this method, we report dielectric constants of 42 ionic liquids at 25 °C.

Place, publisher, year, edition, pages
American Chemical Society , 2011. Vol. 56, no 4, 1494-1499 p.
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Chemical Sciences
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URN: urn:nbn:se:umu:diva-45073DOI: 10.1021/je101184sOAI: oai:DiVA.org:umu-45073DiVA: diva2:425328
Available from: 2011-06-21 Created: 2011-06-21 Last updated: 2017-12-11Bibliographically approved

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Driver, Gordon W
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