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Ionic liquid assisted extraction of nitrogen and sulphur-containing air pollutants from model oil and regeneration of the spent ionic liquid
Umeå University, Faculty of Science and Technology, Department of Chemistry. Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, Turku, Finland. (Technical Chemistry, Chemical–Biological Center)
2011 (English)In: Journal of Environmental Protection, ISSN 2152-2197, E-ISSN 2152-2219, Vol. 2, no 6, 796-802 p.Article in journal (Refereed) Published
Abstract [en]

Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (dodecane) was studied. An ionic liquid (1-ethyl-3-methylimidazolium chloride [C2mim] [Cl]) was used as an extractant. Liquid-liquid extraction by using 1-ethyl-3-methylimidazolium chloride [C2mim] [Cl] was found to be a very promising method for the removal of N- and S-compounds. This was evaluated by using a model oil (dodecane) with indole as a neutral nitrogen compound and pyridine as a basic nitrogen compound. Dibenzothiophene (DBT) was used as a sulphur compound. An extraction capacity of up to 90 wt% was achieved for the model oil containing pyridine, while only 76 wt% of indole in the oil was extracted. The extraction capacity of a model sulphur compound DBT was found to be up to 99 wt%. Regeneration of the spent ionic liquid was carried out with toluene back-extraction. A 1:1 toluene-to-IL wt ratio was performed at room temperature. It was observed that, for the spent ionic liquid containing DBT as a model compound more than 85 wt% (corresponding 3852 mg/kg) could be removed from the oil. After the second regeneration cycle, 86 wt% of the DBT was recovered from the ionic liquid to toluene. In the case of indole as the nitrogen containing species, more than 99 wt%, (corresponding to 2993 mg/kg) of the original indole was transferred from the model oil to the ionic liquid. After the first-regeneration cycle of the spent ionic liquid, 54 wt% of the indole–in-IL was transferred to toluene. Thus, both extractions of nitrogen and sulphur model compounds were successfully carried out from model oil and the back-extraction of these compounds from the ionic liquids to toluene demonstrated the proved the concept of the regeneration point of view.

Place, publisher, year, edition, pages
Scientific Research Publishing, 2011. Vol. 2, no 6, 796-802 p.
Keyword [en]
Ionic Liquids, Extraction, Air Pollutants, Nitrogen Compound, Sulfur Compounds
National Category
Chemical Sciences
URN: urn:nbn:se:umu:diva-45828DOI: 10.4236/jep.2011.26091OAI: diva2:435170
Available from: 2011-08-17 Created: 2011-08-17 Last updated: 2016-09-06Bibliographically approved

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Mikkola, Jyri-Pekka
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