Kinetics of L-arabinose oxidation over supported gold catalysts with in situ catalyst electrical potential measurements
2012 (English)In: Catalysis Science & Technology, ISSN 2044-4753, Vol. 2, 423-431 p.Article in journal (Refereed) Published
The kinetics of L-arabinose selective oxidation over Au/Al2O3 catalysts was studied with simultaneous in situ catalyst electrical potential measurements. An oxidative dehydrogenation mechanism was proposed and a kinetic model taking into account the catalyst potential changes was developed. The kinetic model was implemented into the three-phase system and validated with the experimental observations. The agreement of the kinetic model to the experimental data, in line with the suggested reaction mechanism, was satisfactory.
Place, publisher, year, edition, pages
2012. Vol. 2, 423-431 p.
IdentifiersURN: urn:nbn:se:umu:diva-50082DOI: 10.1039/c1cy00365hISI: 000299291000026OAI: oai:DiVA.org:umu-50082DiVA: diva2:458998
First published on the web 01 Dec 2011 2011-11-242011-11-242012-02-21Bibliographically approved