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One-Pot Liquid-Phase Catalytic Conversion of Ethanol to 1-Butanol over Aluminium Oxide—The Effect of the Active Metal on the Selectivity
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2012 (English)In: Catalysts, Vol. 2, no 1, 68-84 p.Article in journal (Refereed) Published
Abstract [en]

Direct catalytic valorization of bioethanol to 1-butanol over different alumina supported catalysts was studied. Thirteen (13) heterogeneous catalysts were screened in search for the optimal material composition for direct one-pot conversion of ethanol to 1-butanol. For the most promising catalyst, a 25% ethanol conversion with 80% selectivity (among liquid carbon products) to 1-butanol could be reached at 250 °C. Additionally, the reaction kinetics and mechanisms were further investigated upon use of the most suitable catalyst candidate.

Place, publisher, year, edition, pages
2012. Vol. 2, no 1, 68-84 p.
Keyword [en]
heterogeneous catalyst, one-pot; bioethanol, 1-butanol, alumina
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-51264DOI: 10.3390/catal2010068OAI: oai:DiVA.org:umu-51264DiVA: diva2:478214
Note

Published: 13 January 2012

Available from: 2012-01-16 Created: 2012-01-16 Last updated: 2012-09-05Bibliographically approved

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Mikkola, Jyri-Pekka
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