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Acidity in Ionic Liquids
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2011 (English)In: Metals and Materials Processing in a Clean Environment: Volume 3: Molten Salts & Ionic Liquids 2011 / [ed] Florian Kongoli, FLOGEN, 2011, 307-315 p.Conference paper, Published paper (Other academic)
Abstract [en]

A discussion of acidity is developed from the simplest situation - the gas phase. The formation of acids in protic liquids, in solution in molecular liquids and in alreadey ionized liquids is discussed. The distinction between aqueous and other systems, including the question of speciation of actual acidic ions, is emphasized. The measurement of acidity by spectrophotometric and eletrochemical procedures is presented with examples. Tables of selected proton affinities and acidities in a variety of liquids are included.

Place, publisher, year, edition, pages
2011. 307-315 p.
Series
Molten Salts& Ionic Liquids
Keyword [en]
non-aqueous acidity, ionic liquids, pKa, Hammett acidity function, inter-solvent potentials
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-57725OAI: oai:DiVA.org:umu-57725DiVA: diva2:544325
Conference
Fray International Symposium 2011, http://www.flogen.com/FraySymposium/
Available from: 2012-08-14 Created: 2012-08-14 Last updated: 2013-08-09Bibliographically approved

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