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Synthesis, optical power limiting, and DFT calculations of triplet–triplet absorption of three novel Pt(II)-diacetylide chromophores
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2013 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 54, no 19, 2403-2408 p.Article in journal (Refereed) Published
Abstract [en]

Three novel rod-like Pt(II)-diacetylides have been synthesized. When subjected to intense laser light, all three compounds showed strong optical power limiting at 532 and 600 nm. DFT calculated triplet–triplet electronic excitations were found to correlate with the nonlinear absorption.

Place, publisher, year, edition, pages
Elsevier, 2013. Vol. 54, no 19, 2403-2408 p.
Keyword [en]
Platinum acetylide, Optical power limiting, Nonlinear absorption, Triplet–triplet absorption
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-67781DOI: 10.1016/j.tetlet.2013.02.105OAI: oai:DiVA.org:umu-67781DiVA: diva2:614108
Available from: 2013-04-03 Created: 2013-04-03 Last updated: 2017-12-06Bibliographically approved

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