Electrochemical and spectral properties of the polymer form of Cu(II) complex with N,N '-bis(salicylidene)-1,3-propylenediamine
2013 (English)In: Russian journal of general chemistry, ISSN 1070-3632, E-ISSN 1608-3350, Vol. 83, no 3, 423-429 p.Article in journal (Refereed) Published
A conductive polymer based on the Cu(II) complex with N,N'-bis(salicylidene)-1,3-propylenediamine was obtained electrochemically. The optimal mode of the synthesis of the polymer under potentiostatic conditions was found. We determined the charge diffusion coefficient and activation barrier and elucidated the nature of the limiting step of the charge transfer in the polymer bulk in the electrolyte medium. The azomethine base, Cu(II) complex, and its polymer form in the oxidized and reduced states were characterized by X-ray photoelectron spectroscopy and electron absorption spectroscopy.
Place, publisher, year, edition, pages
2013. Vol. 83, no 3, 423-429 p.
IdentifiersURN: urn:nbn:se:umu:diva-72711DOI: 10.1134/S1070363213030031ISI: 000317980200003OAI: oai:DiVA.org:umu-72711DiVA: diva2:626910