umu.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Pressure-induced transformation and superhard phase in fullerenes: the effect of solvent intercalation
Show others and affiliations
2013 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 103, no 7, 071913- p.Article in journal (Refereed) Published
Abstract [en]

We studied the behavior of solvated and desolvated C-60 crystals under pressure by in situ Raman spectroscopy. The pressure-induced bonding change and structural transformation of C60s are similar in the two samples, both undergoing deformation and amorphization. Nevertheless, the high pressure phases of solvated C-60 can indent diamond anvils while that of desolvated C(60)s cannot. Further experiments suggest that the solvents in the solvated C-60 act as both spacers and bridges by forming covalent bonds with neighbors in 3D network at high pressure, and thus, a fraction of fullerenes may preserve the periodic arrangement in spite of their amorphization.

Place, publisher, year, edition, pages
2013. Vol. 103, no 7, 071913- p.
Keyword [en]
Fullerene, C60, intercalation, solvent, hydrocarbon, xylene, high pressure, diamond anvil cell, superhard
National Category
Physical Sciences
Research subject
Physics
Identifiers
URN: urn:nbn:se:umu:diva-81012DOI: 10.1063/1.4818909ISI: 000323769000028OAI: oai:DiVA.org:umu-81012DiVA: diva2:652440
Funder
Swedish Research Council, 621-2010-3732
Available from: 2013-09-30 Created: 2013-09-30 Last updated: 2017-12-06Bibliographically approved

Open Access in DiVA

fulltext(757 kB)164 downloads
File information
File name FULLTEXT01.pdfFile size 757 kBChecksum SHA-512
ff0e2d7ecb3e36543d92c60ea001a743303e1c0aeea1878f50a1cae5652117bb883ab03e057ed67675b067ec50f8d923dce1c99d672711c94a1b117b03695c62
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Search in DiVA

By author/editor
Yao, MingguangSundqvist, Bertil
By organisation
Department of Physics
In the same journal
Applied Physics Letters
Physical Sciences

Search outside of DiVA

GoogleGoogle Scholar
Total: 164 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 101 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf