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Equilibrium and Structural Studies of Silicon(IV) and Aluminium(III) in Aqueous Solution: 1. The Formation of Ternary Mononuclear and Polynuclear Complexes in the System Al(3+)--Gallic Acid--OH-. A Potentiometric Study in 0.6 M Na(Cl)
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
1981 (English)In: Acta Chemica Scandinavica, ISSN 0302-4377, Vol. A 35, 201-212 p.Article in journal (Refereed) Published
Place, publisher, year, edition, pages
Acta Chemica Scandinavica , 1981. Vol. A 35, 201-212 p.
National Category
Chemical Sciences
URN: urn:nbn:se:umu:diva-94440DOI: 10.3891/acta.chem.scand.35a-0201OAI: diva2:753871
Available from: 2014-10-09 Created: 2014-10-09 Last updated: 2014-10-09Bibliographically approved
In thesis
1. Equilibrium studies of ternary aluminium(III) hydroxo complexes with ligands related to conditions in natural waters
Open this publication in new window or tab >>Equilibrium studies of ternary aluminium(III) hydroxo complexes with ligands related to conditions in natural waters
1983 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The thesis is a summary and discussion of eight papers. During the last decades, precipitation has become increasingly acidic due to the extensive use of fossil fuels. In areas of poorly buffered bedrocks, e.g. Scandinavia, northeastern United States, this phenomenon has resulted in elevated amounts of Al(III) being leached into streams and lakes. Recent findings reveal that these elevated Al-concentrations could cause fish death and decreasing forest production.

In the present thesis, the importance of taking naturally occurring substances into consideration when discussing Al(III) in natural waters, is emphasized. On the basis of a chemical characterization of relevant ligand classes in a natural water, the complex formation between Al^+, hydroxide ions and the inorganic ligand carbonic acid, the low-molecular weight organic ligand citric acid and the high-molecular weight model substances gallic acid, 1,2-dihydroxynaphtha-lene-4-sulfonate, 1,2-naphthoquinone-4-sulfonate, pyrocatechol and salicylic acid were investigated. The investigations were performed as series of Potentiometrie titrations and data were processed by means of the least-squares computer program LETAGROPVRID using a technique called pqr-analysis, permitting an unbiased search for complex model (and corresponding equilibrium constants) to be made. In most systems studied, the complexation at high ligand excesses can be described by a series of mononuclear complexes AIL-AIL^. Tentatively, the whole series consists of octahedrally coordinated (water and ligand oxygens) AI(III). At lower ligand excesses, the significance and in some cases even predominance of ternary mono- and polynuclear hydroxo complexes is demonstrated. In two of the systems, binary aluminium hydroxo species are evaluated.

The potential importance of the substances with respect to Al-com-plexation in natural waters are indicated in a number of model calculations. The solubility of the clay mineral kaolinite is calculated as a function of -lg[H+] and ligand concentration. It is shown that citric acid, gallic acid, 1,2-dihydroxynaphthalene-4-sulfonate, pyrocatechol and salicylic acid contribute quite significant to the total solubilities, even at very low concentrations.

As a complement and background to the equilibrium studies, the corrosion rate for one of the naturally occurring Al-bearing minerals, corundum, is reported. In this investigation, performed with a leach-ant solution of ground-water composition, an experimental technique was employed which made it possible to divide the corrosion into chemical and mechanical losses.

Place, publisher, year, edition, pages
Umeå: Umeå universitet, 1983. 45 p.
aqueous solution, binary and ternary hydroxo complexes of Al3+, carbonic acid, citric acid, phenolic ligands, emf-titrations, equilibrium analysis, model calculations towards natural waters
National Category
Chemical Sciences
urn:nbn:se:umu:diva-94116 (URN)91-7174-124-0 (ISBN)
Public defence
1983-05-20, Kemiska institutionen, sal B, Lu0, Umeå universitet, Umeå, 10:00

Diss. (sammanfattning) Umeå : Umeå universitet, 1983

Available from: 2014-10-09 Created: 2014-10-03 Last updated: 2015-04-10Bibliographically approved

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Öhman, Lars-OlofSjöberg, Staffan
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