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Effects of temperature and residence time on continuous torrefaction of spruce wood
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics. (Anders Nordin)ORCID iD: 0000-0002-1874-6447
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
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2015 (English)In: Fuel processing technology, ISSN 0378-3820, Vol. 134, 387-398 p.Article in journal (Refereed) Published
Abstract [en]

As a solid energy carrier, biomass generally has a few disadvantages, which limits its use for coal replacement and as a feedstock for entrained flow gasification. The hydrophilic and fibrous nature, the low calorific value and low bulk energy content imply high accumulated costs in the whole supply chain and severe challenges in more advanced conversion systems. By thermally pretreating the biomass by torrefaction, these properties may be significantly improved. A continuous torrefaction rotary drum reactor was designed, constructed and evaluated to enable an accurate process control and allow a homogeneous well-defined high quality product to be produced. The combined effects of torrefaction temperature (260–310 °C) and residence time (8–25 min) on a large number of product properties (> 25) were determined for Norway spruce. The resulting mass and energy yields were 46–97% and 62–99%, respectively. Exothermic reactions were evident both at low (260 °C) and high temperatures (310 °C) but with no thermal runaway observed. Increased torrefaction severity resulted in decreased milling energy consumption, angle of repose, mass and energy yield, content of volatile matter, hydrogen, cellulose and hemicellulose. Hydrophobicity, heating value, carbon and fixed carbon contents increased. For all responses, the effect of torrefaction temperature was larger than the effect of residence time. Substantial interaction effects were present for mass and energy yields, volatile matter and hydrogen content. Another correlation found was the relationship of hemicellulose degradation and the brittleness of the torrefied product. Data also suggest secondary char forming reactions during the torrefaction process, resulting in higher fixed carbon content in the torrefied material than expected. The results also suggest torrefaction temperature and residence time not to be totally interchangeable.

Place, publisher, year, edition, pages
2015. Vol. 134, 387-398 p.
Keyword [en]
Torrefaction, Hydrophobicity, Grindability, Rotary drum, Continuous reactor
National Category
Chemical Process Engineering
URN: urn:nbn:se:umu:diva-103041DOI: 10.1016/j.fuproc.2015.02.021ISI: 000353739200047OAI: diva2:812232
Bio4EnergySwedish Energy Agency, 31489-1
Available from: 2015-05-18 Created: 2015-05-18 Last updated: 2015-06-11Bibliographically approved
In thesis
1. From torrefaction to gasification: Pilot scale studies for upgrading of biomass
Open this publication in new window or tab >>From torrefaction to gasification: Pilot scale studies for upgrading of biomass
2015 (English)Doctoral thesis, comprehensive summary (Other academic)
Alternative title[sv]
Från torrefiering till förgasning : Experiment i pilotskala för förädling av biomassa
Abstract [en]

Increasing the share of biomass, preferably by replacing fossil fuels, is one way to mitigate the present climate change. Fossil coal can be directly replaced by co-combustion of coal and biomass and fossil engine fuels (gasoline and diesel) could potentially partly be replaced by synthetic renewable fuels produced via entrained flow gasification of biomass. The use of biomass in these processes is so far limited, partly because of the fibrous and hygroscopic nature of biomass which leads to problem in storing, transportation, handling and feeding.

This thesis demonstrates how the challenging characteristics of raw biomass are mitigated by the pretreatment method torrefaction. Torrefaction is a process where biomass is heated in an oxygen deficient atmosphere to typically between 240 and 350°C for a time period of 2 minutes to 1 hour. Most of the torrefaction R&D in the literature have so far been performed with bench-scale batch reactors. For the purpose of carefully studying continuous torrefaction, a 20 kg/h torrefaction pilot plant was therefore designed, constructed and evaluated.

The overall conclusion from this thesis is that the many benefits of torrefied biomass are valid also when produced with a continuous pilot plant and for typically Swedish forest biomasses. Some of the documented improved biomass properties are increased heating value, increased energy density, higher friability (lower milling energy) and less hydrophilic biomass (less moisture uptake). Most of the improvements can be attributed to the decomposition of hemicellulose and cellulose during torrefaction.

The most common variables for describing the torrefaction degree are mass yield or anhydrous weight loss but both are challenging to determine for continuous processes. We therefore evaluated three different methods (one existing and two new suggestions) to determine degree of torrefaction that not require measurement of mass loss. The degree of torrefaction based on analyzed higher heating value of the raw and torrefied biomass (DTFHHV) predicted mass yield most accurate and had lowest combined uncertainty.

Pelletizing biomass enhance transportation and handling but results from pelletization of torrefied biomass is still very limited in the literature and mainly reported from single pellet presses. A pelletization study of torrefied spruce with a ring die in pilot scale was therefore performed. The bulk energy density was found to be 14.6 GJ/m3 for pelletized torrefied spruce (mass yield 75%), a 40% increase compared to regular white pellets and therefore are torrefied pellets more favorable for long distance transports. More optimization of the torrefied biomass and the pelletization process is though needed for acquiring industrial quality pellets with lower amount of fines and higher pellet durability than attained in the present study.

Powders from milled raw biomass are generally problematic for feeding and handling and torrefied biomass has been proposed to mitigate these issues. The influence of torrefaction and pelletization on powder and particle properties after milling was therefore studied. The results show that powder from torrefied biomass were enhanced with higher bulk densities, lower angle of repose as well as smaller less elongated particles with less surface roughness. Even higher powder qualities were achieved by pelletizing the torrefied biomass before milling, i.e. another reason for commercial torrefied biomass to be pelletized.

Entrained flow gasification (EFG) is a promising option for conversion of biomass to other more convenient renewable energy carriers such as electricity, liquid biofuels and green petrochemicals. Also for EFGs are torrefied fuels very limited studied. Raw and torrefied logging residues were successfully gasified in a pilot scale pressurized entrained flow biomass gasifier at 2 bar(a) with a fuel feed corresponding to 270 kWth. Significantly lower methane content (50% decrease) in the syngas was also demonstrated for the torrefied fuel with mass yield 49%. The low milling energy consumption for the torrefied fuels compared to the raw fuel was beneficial for the gasification plant efficiency.

Place, publisher, year, edition, pages
Umeå: Umeå universitet, 2015. 58 p.
Torrefaction, biomass, pilot scale, continuous reactor, grindability, entrained flow gasification, degree of torrefaction, biomass powder
National Category
Chemical Process Engineering
urn:nbn:se:umu:diva-103046 (URN)978-91-7601-287-1 (ISBN)
Public defence
2015-06-10, N450, Naturvetarhuset, Umeå universitet, Umeå, 13:00 (English)
Available from: 2015-05-20 Created: 2015-05-18 Last updated: 2015-05-20Bibliographically approved

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Strandberg, MartinOlofsson, IngemarPommer, LindaWiklund-Lindström, SusanneÅberg, KatarinaNordin, Anders
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