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Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe-2(mμ-SCHR2)(2)(NO)(4)], R = Me, Ph
Russia.
Russia.
Russia.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
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2015 (English)In: Polyhedron, ISSN 0277-5387, E-ISSN 1873-3719, Vol. 90, 197-201 p.Article in journal (Refereed) Published
Abstract [en]

New dinitrosyl iron complexes of binuclear structure [Fe-2(mu-SCHMe2)(2)(NO)(4)] and [Fe-2(mu-SCHPh2)(2)(NO)(4)] were first synthesized employing new method from Fe(CO)(5), corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied.

Place, publisher, year, edition, pages
Elsevier, 2015. Vol. 90, 197-201 p.
Keyword [en]
Crystal structure, Thiolate ligands, Dinitrosyl iron complex, Nitric oxide donor, DFT calculations
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-103142DOI: 10.1016/j.poly.2015.02.009ISI: 000352663900026OAI: oai:DiVA.org:umu-103142DiVA: diva2:813392
Available from: 2015-05-22 Created: 2015-05-18 Last updated: 2017-12-04Bibliographically approved

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Shchukarev, Andrey

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