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Domino Twofold Heck/6π-Electrocyclization Reactions of 1,2-Dihaloalkenes
Umeå University, Faculty of Science and Technology, Department of Chemistry. Institute of Chemistry, University of Rostock, Rostock, Germany.
2012 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, no 19, 2735-2744 p.Article in journal (Refereed) Published
Abstract [en]

Domino twofold Heck/6 pi-electrocyclization reactions of 1,2-dihaloalkenes allow for a convenient synthesis of benzene derivatives. In recent years, this strategy has been applied to various 1,2-dihalogenated carbocyclic alkenes and heterocycles, and a variety of benzo-fused ring systems have been prepared. The electrocyclization reactions proceed well for five-membered, but not for six-membered heterocycles.

Place, publisher, year, edition, pages
Georg Thieme Verlag KG, 2012. no 19, 2735-2744 p.
Keyword [en]
electrocyclization reactions, domino reactions, Heck reaction, palladium, heterocycles
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-104245DOI: 10.1055/s-0032-1317192ISI: 000311492100003OAI: oai:DiVA.org:umu-104245DiVA: diva2:819894
Available from: 2015-06-11 Created: 2015-06-09 Last updated: 2017-12-04Bibliographically approved

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