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Chemo-Bio Catalyzed Synthesis of R-1-Phenylethyl Acetate over Bimetallic PdZn Catalysts, Lipase, and Ru/Al2O3: part II
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2011 (English)In: Kinetics and catalysis, ISSN 0023-1584, E-ISSN 1608-3210, Vol. 52, no 1, 77-81 p.Article in journal (Refereed) Published
Abstract [en]

One-pot synthesis of R-1-phenyethylacetate at 70 degrees C was investigated using three different catalysts simultaneously, namely a bimetallic PdZn/Al2O3 as a hydrogenation catalyst, an immobilized lipase as an acylation catalyst and Ru/Al2O3 as a racemization catalyst. The most active bimetallic catalyst was PdZn/Al2O3 calcined at 300 degrees C and reduced at 400 degrees C, whereas the most selective although less active catalyst was the one being calcined and reduced at 500 degrees C. The highest selectivity to R-1-phenylethyl acetate over this catalyst was 32 at 48% conversion. Ru/Al2O3 was confirmed to have a positive effect on the formation of the desired product, although it was not very active in the racemization during one-pot synthesis.

Place, publisher, year, edition, pages
Maik Nauka/Interperiodica, 2011. Vol. 52, no 1, 77-81 p.
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Physical Chemistry
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URN: urn:nbn:se:umu:diva-104537DOI: 10.1134/S0023158411010095ISI: 000289260900012OAI: oai:DiVA.org:umu-104537DiVA: diva2:822449
Available from: 2015-06-16 Created: 2015-06-11 Last updated: 2017-12-04Bibliographically approved

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Shchukarev, AndreyBoström, DanMikkola, Jyri-Pekka

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Shchukarev, AndreyBoström, DanMikkola, Jyri-Pekka
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Department of ChemistryDepartment of Applied Physics and Electronics
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Kinetics and catalysis
Physical Chemistry

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