Change search
ReferencesLink to record
Permanent link

Direct link
Polarized Raman study of aligned multiwalled carbon nanotubes arrays under high pressure
Show others and affiliations
2015 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 119, no 49, 27759-27767 p.Article in journal (Refereed) Published
Abstract [en]

Tuning the intertube interaction and the topological structure of carbon nanotubes by the application of pressure may obviously affect their properties such as optical and electronic properties. However, characterizing such changes is still challenging. Here, we performed polarized Raman scattering studies on aligned multiwalled carbon nanotube arrays (MWNTAs). Unlike researchers from the previous literature, we found that the MWNTAs exhibit a polarization dependence similar to that of isolated single walled carbon nanotubes at ambient conditions. Upon compression, the polarization dependence weakens gradually with increasing pressure up to ∼20 GPa, which has been discussed in terms of pressure-induced enhancement of intertube interactions. At around 20 GPa, the depolarization effect vanishes, which can be explained by the formation of interlinked sp3 bonding in the MWNTAs. Our results show that polarized Raman spectroscopy is an efficient method to explore not only intertube interaction but also structural transition changes in MWNTs, which overcome the difficulty that MWNTs have no obvious fingerprints like those of single-walled carbon nanotubes in the study of structural transformations.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2015. Vol. 119, no 49, 27759-27767 p.
Keyword [en]
Carbon nanotubes, carbon nanotube arrays, intertube interaction, high pressure, polarized Raman scattering
National Category
Condensed Matter Physics
Research subject
URN: urn:nbn:se:umu:diva-113766DOI: 10.1021/acs.jpcc.5b08161ISI: 000366339000068OAI: diva2:889683
Available from: 2015-12-28 Created: 2015-12-28 Last updated: 2016-03-13Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Sundqvist, Bertil
By organisation
Department of Physics
In the same journal
The Journal of Physical Chemistry C
Condensed Matter Physics

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 21 hits
ReferencesLink to record
Permanent link

Direct link