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Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry. Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FIN-20500, Turku/Åbo, Finland.
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry. Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FIN-20500, Turku/Åbo, Finland.
2016 (English)In: Chemical Engineering Science, ISSN 0009-2509, E-ISSN 1873-4405, Vol. 142, 310-317 p.Article in journal (Refereed) Published
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Abstract [en]

Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

Place, publisher, year, edition, pages
2016. Vol. 142, 310-317 p.
Keyword [en]
Ethyl chloride, Kinetic modeling, Gas-phase reaction, Heterogeneous catalysis
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-114093DOI: 10.1016/j.ces.2015.12.005ISI: 000369068500027OAI: oai:DiVA.org:umu-114093DiVA: diva2:893633
Available from: 2016-01-13 Created: 2016-01-13 Last updated: 2016-03-29Bibliographically approved

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Bukhanko, NataliaWärnå, JohanSamikannu, AjaikumarMikkola, Jyri-Pekka
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