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Ionic liquids derived from organosuperbases: en route to superionic liquids
Umeå University, Faculty of Science and Technology, Department of Chemistry. Industrial Chemistry & Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University.
2016 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 6, no 11, 9194-9208 p.Article, review/survey (Refereed) PublishedText
Abstract [en]

Interest in ionic liquids with guanidine, amidine and other superbasic cations has grown markedly in recent years. The syntheses, characterization and properties of protic and quaternary alkylated salts based on cyclic or acyclic guanidine and amidine derivatives have been described in detail. By modifying the anion or the cation, a wide range of properties of superbasic ionic liquids can be tuned, including viscosity, melting point, density, conductivity, solubility, liquid range, and thermal and hydrolytic stability. They are promising solvents for electrochemical, photovoltaic and various synthetic applications, in particular as specific catalysts. Owing to their specific properties, superbasic ionic liquids can be used in applications of great industrial importance such as CO2, SO2 or COS chemisorption.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2016. Vol. 6, no 11, 9194-9208 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-116808DOI: 10.1039/c5ra23616aISI: 000369515900080OAI: oai:DiVA.org:umu-116808DiVA: diva2:902685
Available from: 2016-02-12 Created: 2016-02-12 Last updated: 2016-03-16Bibliographically approved

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Mikkola, Jyri-Pekka
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