Change search
ReferencesLink to record
Permanent link

Direct link
The first example of cobalt(III) mu-oxoacetate with water molecules in apical positions
Show others and affiliations
2008 (English)In: Russian journal of general chemistry, ISSN 1070-3632, E-ISSN 1608-3350, Vol. 78, no 11, 2006-2012 p.Article in journal (Refereed) PublishedText
Abstract [en]

Oxidation of Co(MeCOO)(2)center dot 4H(2)O with ozone in acetic acid followed by the treatment with nitric acid results in the formation of the trinuclear oxo-centered acetate complex [Co(III) (3)(mu(3)-O)(mu-O(2)CMe)(6)(OH(2))(3)] NO(3)center dot MeCOOH ([I]NO(3)center dot MeCOOH). Reasons of a decrease in the idealized symmetry of molecular structure (D (3h) -> D (3)) of the complex cation [I](+) were analyzed by means of quantum-chemical calculations. The complex does not retain its structure in solutions (in water, methanol, and ethanol).

Place, publisher, year, edition, pages
New York: Maik Nauka/Interperiodica, 2008. Vol. 78, no 11, 2006-2012 p.
National Category
Chemical Sciences
URN: urn:nbn:se:umu:diva-117476DOI: 10.1134/S1070363208110042ISI: 000261959400004OAI: diva2:911587
Available from: 2016-03-14 Created: 2016-03-01 Last updated: 2016-03-14Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Shchukarev, Andrey V
By organisation
Department of Chemistry
In the same journal
Russian journal of general chemistry
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 13 hits
ReferencesLink to record
Permanent link

Direct link