The first example of cobalt(III) mu-oxoacetate with water molecules in apical positions
2008 (English)In: Russian journal of general chemistry, ISSN 1070-3632, E-ISSN 1608-3350, Vol. 78, no 11, 2006-2012 p.Article in journal (Refereed) PublishedText
Oxidation of Co(MeCOO)(2)center dot 4H(2)O with ozone in acetic acid followed by the treatment with nitric acid results in the formation of the trinuclear oxo-centered acetate complex [Co(III) (3)(mu(3)-O)(mu-O(2)CMe)(6)(OH(2))(3)] NO(3)center dot MeCOOH ([I]NO(3)center dot MeCOOH). Reasons of a decrease in the idealized symmetry of molecular structure (D (3h) -> D (3)) of the complex cation [I](+) were analyzed by means of quantum-chemical calculations. The complex does not retain its structure in solutions (in water, methanol, and ethanol).
Place, publisher, year, edition, pages
New York: Maik Nauka/Interperiodica, 2008. Vol. 78, no 11, 2006-2012 p.
IdentifiersURN: urn:nbn:se:umu:diva-117476DOI: 10.1134/S1070363208110042ISI: 000261959400004OAI: oai:DiVA.org:umu-117476DiVA: diva2:911587