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The first example of cobalt(III) mu-oxoacetate with water molecules in apical positions
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2008 (English)In: Russian journal of general chemistry, ISSN 1070-3632, E-ISSN 1608-3350, Vol. 78, no 11, 2006-2012 p.Article in journal (Refereed) PublishedText
Abstract [en]

Oxidation of Co(MeCOO)(2)center dot 4H(2)O with ozone in acetic acid followed by the treatment with nitric acid results in the formation of the trinuclear oxo-centered acetate complex [Co(III) (3)(mu(3)-O)(mu-O(2)CMe)(6)(OH(2))(3)] NO(3)center dot MeCOOH ([I]NO(3)center dot MeCOOH). Reasons of a decrease in the idealized symmetry of molecular structure (D (3h) -> D (3)) of the complex cation [I](+) were analyzed by means of quantum-chemical calculations. The complex does not retain its structure in solutions (in water, methanol, and ethanol).

Place, publisher, year, edition, pages
New York: Maik Nauka/Interperiodica, 2008. Vol. 78, no 11, 2006-2012 p.
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Chemical Sciences
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URN: urn:nbn:se:umu:diva-117476DOI: 10.1134/S1070363208110042ISI: 000261959400004OAI: oai:DiVA.org:umu-117476DiVA: diva2:911587
Available from: 2016-03-14 Created: 2016-03-01 Last updated: 2016-03-14Bibliographically approved

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Shchukarev, Andrey V
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Department of Chemistry
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ReferencesLink to record
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