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Thermodynamic evaluation and optimization of the (Na2SO4+K2SO4+Na2S2O7+K2S2O7) system
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics, Energy Technology and Thermal Process Chemistry. Åbo Akademi Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500 Turku, Finland.
2006 (English)In: Journal of Chemical Thermodynamics, ISSN 0021-9614, E-ISSN 1096-3626, Vol. 38, no 12, 1568-1583 p.Article in journal (Refereed) PublishedText
Abstract [en]

A complete, critical evaluation of all phase diagram and thermodynamic data was performed for all phases of the (Na2SO4 + K2SO4 + Na2S2O7 + K2S2O7) system and optimized model parameters were obtained. The Modified Quasichemical Model in the Quadruplet Approximation was used for modelling the liquid phase. The model evaluates first- and second-nearest-neighbour short-range ordering, where the cations (Na+ and K+) are assumed to mix on a cationic sublattice. The Compound Energy Formalism was used for modelling the solid Solutions of (Na,K)(2)SO4 and (Na,K)(2)S2O7. The models can be used to predict the thermodynamic properties and phase equilibria in multicomponent heterogeneous systems. The experimental data from the literature were reproduced within experimental error limits.

Place, publisher, year, edition, pages
London: Academic Press, 2006. Vol. 38, no 12, 1568-1583 p.
Keyword [en]
thermodynamic modelling, alkali sulphate, alkali pyrosulphate, molten salt, Modified Quasichemical Model
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-119370DOI: 10.1016/j.jct.2006.04.002ISI: 000243356000011OAI: oai:DiVA.org:umu-119370DiVA: diva2:928729
Available from: 2016-05-16 Created: 2016-04-18 Last updated: 2016-05-16Bibliographically approved

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Backman, Rainer
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