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  • 1. Abou-Hamad, E.
    et al.
    Babaa, M. -R
    Bouhrara, M.
    Kim, Y.
    Saih, Y.
    Dennler, S.
    Mauri, F.
    Basset, J. -M
    Goze-Bac, C.
    Wågberg, Thomas
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Structural properties of carbon nanotubes derived from (13)C NMR2011In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 84, no 16, 165417- p.Article in journal (Refereed)
    Abstract [en]

    We present a detailed experimental and theoretical study on how structural properties of carbon nanotubes can be derived from 13C NMR investigations. Magic angle spinning solid state NMR experiments have been performed on single-and multiwalled carbon nanotubes with diameters in the range from 0.7 to 100 nm and with number of walls from 1 to 90. We provide models on how diameter and the number of nanotube walls influence NMR linewidth and line position. Both models are supported by theoretical calculations. Increasing the diameter D, from the smallest investigated nanotube, which in our study corresponds to the inner nanotube of a double-walled tube to the largest studied diameter, corresponding to large multiwalled nanotubes, leads to a 23.5 ppm diamagnetic shift of the isotropic NMR line position d. We show that the isotropic line follows the relation d = 18.3/D + 102.5 ppm, where D is the diameter of the tube and NMR line position d is relative to tetramethylsilane. The relation asymptotically tends to approach the line position expected in graphene. A characteristic broadening of the line shape is observed with the increasing number of walls. This feature can be rationalized by an isotropic shift distribution originating from different diamagnetic shielding of the encapsulated nanotubes together with a heterogeneity of the samples. Based on our results, NMR is shown to be a nondestructive spectroscopic method that can be used as a complementary method to, for example, transmission electron microscopy to obtain structural information for carbon nanotubes, especially bulk samples.

  • 2. Abou-Hamad, E.
    et al.
    Kim, Y.
    Bouhrara, M.
    Saih, Y.
    Wågberg, Thomas
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Luzzi, D. E.
    Goze-Bac, C.
    NMR strategies to study the local magnetic properties of carbon nanotubes2012In: Physica. B, Condensed matter, ISSN 0921-4526, Vol. 407, no 4, 740-742 p.Article in journal (Refereed)
    Abstract [en]

    The local magnetic properties of the one dimensional inner space of the nanotubes are investigated using C-13 nuclear magnetic resonance spectroscopy of encapsulated fullerene molecules inside single walled carbon nanotubes. Isotope engineering and magnetically purified nanotubes have been advantageously used on our study to discriminate between the different diamagnetic and paramagnetic shifts of the resonances. Ring currents originating from the pi electrons circulating on the nanotube, are found to actively screen the applied magnetic field by -36.9 ppm. Defects and holes in the nanotube walls cancel this screening locally. What is interesting, that at high magnetic fields, the modifications of the NMR resonances of the molecules from free to encapsulated can be exploited to determine some structural characteristics of the surrounding nanotubes, never observed experimentally. (C) 2011 Elsevier B.V. All rights reserved.

  • 3.
    Abou-Hamad, Edy
    et al.
    Universite Montpellier II.
    Kim, Y
    University of Pennsylvania.
    Talyzin, Alexandr
    Umeå University, Faculty of Science and Technology, Physics.
    Goze-Bac, Christophe
    Universite Montpellier II.
    Luzzi, David
    University of Pennsylvania.
    Rubio, Angelo
    University of Basque Country.
    Wågberg, Thomas
    Umeå University, Faculty of Science and Technology, Physics.
    Hydrogenation of C-60 in Peapods: Physical Chemistry in Nano Vessels2009In: The Journal of Physical Chemistry C, ISSN 1932-7447, Vol. 113, no 20, 8583-8587 p.Article in journal (Refereed)
    Abstract [en]

    Hydrogenation of C-60 molecules inside SWNT was achieved by direct reaction with hydrogen gas at elevated pressure and temperature. Evidence for the C-60 hydrogenation in peapods is provided by isotopic engineering with specific enrichment of encapsulated species and high resolution C-13 and H-1 NMR spectroscopy with the observation of characteristic diamagnetic and paramagnetic shifts of the NMR lines and the appearance of sp(3) carbon resonances. We estimate that approximately 78% of the C-60 molecules inside SWNTs are hydrogenated to an average degree of 14 hydrogen atoms per C-60 molecule. As a consequence, the rotational dynamics of the encapsulated C60Hx molecules is clearly hindered. Our successful hydrogenation experiments open completely new roads to understand and control confined chemical reactions at the nano scale

  • 4.
    Abou-Hamad, Edy
    et al.
    Universite Montpellier 2, France.
    Kim, Y.
    University of Pennsylvania, Philadelphia.
    Wågberg, Thomas
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Boesch, D.
    University of California at Berkeley, and Materials Sciences Division, Lawrence Berkeley National Laboratory.
    Aloni, S.
    University of California at Berkeley, and Materials Sciences Division, Lawrence Berkeley National Laboratory.
    Zettl, Alex
    University of California at Berkeley, and Materials Sciences Division, Lawrence Berkeley National Laboratory.
    Rubio, Angelo
    Universidad del Pas Vasco UPV/EHU.
    Luzzi, David E.
    University of Pennsylvania, Philadelphia.
    Goze-Bac, Christophe
    CNRS Universit Montpellier 2.
    Molecular dynamics and phase transition in one-dimensional crystal of C60 encapsulated inside single wall carbon nanotubes2009In: ACS Nano, ISSN 1936-0851, Vol. 3, no 12, 3878-3883 p.Article in journal (Refereed)
    Abstract [en]

    One-dimensional crystals of 25% 13C-enriched C60 encapsulated inside highly magnetically purified SWNTs were investigated by following the temperature dependence of the 13C NMR line shapes and the relaxation rates from 300 K down to 5 K. High-resolution MAS techniques reveal that 32% of the encapsulated molecules, so-called the C60α, are blocked at room temperature and 68%, labeled C60β, are shown to reversly undergo molecular reorientational dynamics. Contrary to previous NMR studies, spin−lattice relaxation time reveals a phase transition at 100 K associated with the changes in the nature of the C60β dynamics. Above the transition, the C60β exhibits continuous rotational diffusion; below the transition, C60β executes uniaxial hindered rotations most likely along the nanotubes axis and freeze out below 25 K. The associated activation energies of these two dynamical regimes are measured to be 6 times lower than in fcc-C60, suggesting a quiet smooth orientational dependence of the interaction between C60β molecules and the inner surface of the nanotubes.

  • 5.
    ABUDULIMU, ABASI
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Effectof Growth Time, Growth Temperature and Light  on Growth Mechanism of C60 nanorods2013Independent thesis Advanced level (degree of Master (Two Years)), 10 credits / 15 HE creditsStudent thesis
    Abstract [en]

    In this thesis work C60 nanorods were produced by Liquid-Liquid Interfacial Precipitation method (LLIP) assisted with 10 s of weak sonication. Ethanol and m-dichlorobenzene were used as poor and good solvents of C60, respectively. Five different temperatures, 4, 10, 20, 30, 40 and 50                         , were chosen as growth temperatures of different samples to investigate the effect of temperature on the grown structures. Different samples were prepared in the dark and under the light with various growth time to determine the effect of light and growth time on growth of C60 nanorods. The characterization of the grown C60 nanorods were conducted by transmission electron microscopy (TEM) and x-ray diffraction (XRD). The result of characterization indicated that the sonication introduced smaller C60 nanostructures; light irradiation and temperature increase (till 40 C0) during the growth time resulted in nanorods with smaller diameter, whereas the long growth time lead to the increase of the diameter of C60 nanorods. The as-grown C60 nanorods synthesized at different conditions possess an hcp crystal structure.    

  • 6. Ajuria, Jon
    et al.
    Arnaiz, Maria
    Botas, Cristina
    Carriazo, Daniel
    Mysyk, Roman
    Rojo, Teofilo
    Talyzin, Alexandr V.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Goikolea, Eider
    Graphene-based lithium ion capacitor with high gravimetric energy and power densities2017In: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 363, 422-427 p.Article in journal (Refereed)
    Abstract [en]

    Hybrid capacitor configurations are now of increasing interest to overcome the current energy limitations of supercapacitors. In this work, we report a lithium ion capacitor (LIC) entirely based on graphene. On the one hand, the negative-battery-type- electrode consists of a self-standing, binder-free 3D macroporous foam formed by reduced graphene oxide and decorated with tin oxide nanoparticles (SnO2-rGO). On the other hand, the positive-capacitor-type- electrode is based on a thermally expanded and physically activated reduced graphene oxide (a-TEGO). For comparison purposes, a symmetric electrical double layer capacitor (EDLC) using the same activated graphene in 1.5 M Et4NBE4/ACN electrolyte is also assembled. Built in 1 M LiPF6 EC:DMC, the graphene-based LIC shows an outstanding, 10-fold increase in energy density with respect to its EDLC counterpart at low discharge rates (up to 200 Wh kg(-1)). Furthermore, it is still capable to deliver double the energy in the high power region, within a discharge time of few seconds.

  • 7. Aksenova, N.A.
    et al.
    Isakina, A.P.
    Prokhvatilov, A.I.
    Strzhemechny, M.A.
    Soldatov, Alexander V.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Structure studies of C60 polymerized at low pressures1997In: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, vol. 5, Pennington, NJ: The Electrochemical Society , 1997, 687-694 p.Conference paper (Refereed)
    Abstract [en]

    The structure and lattice properties of a polymerized C60 sample were investigated by X-ray powder diffraction over the range from liquid-nitrogen to room temperature. The aim of these studies was to establish the effect of low-pressure compression (up to 1.1 GPa) on the phase composition of the sample, to determine the structure of the phases involved, to obtain the variation of the lattice parameters with temperature, to observe eventual phase transformation in polymerized C60, and to elucidate the evolution of the orientational order with varying temperature. Analysis of the room-temperature diffraction patterns indicates that the sample contained at least two major phases, namely rhombohedral and and tetragonal with the polymerization array close to two-dimensional. Our data obtained on samples annealed at 300 C in the air allow us to conclude that polymerized C60 converts to a mixture of the fcc structure plus a new phase, presumably C60O.

  • 8. Aleksandrovskii, A. N.
    et al.
    Dolbin, A.V.
    Esel'son, V.B.
    Gavrilko, V.G.
    Manzhelii, V.G.
    Udovidchenko, B.G.
    Bakai, A.S.
    Gadd, G.E.
    Moricca, S.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Low-temperature thermal expansion of pure and inert gas-doped fullerite C602003In: Fizika Nizkikh Temperatur (Kharkov), ISSN 0132-6414 (Print) 1816-0328 (On-line), Vol. 29, no 4, 432-442 p.Article in journal (Refereed)
    Abstract [en]

    The low temperature (2–24 K) thermal expansion of pure (single-crystal and polycrystalline) C60 and polycrystalline C60 intercalated with He, Ne, Ar, and Kr has been investigated using the high-resolution capacitance dilatometer. The investigation of the time dependence of the sample length variations deltaL(t) on heating by deltaT shows that the thermal expansion is determined by the sum of positive and negative contributions, which have different relaxation times. The negative thermal expansion usually prevails at helium temperatures. The positive expansion is connected with the phonon thermalization of the system. The negative expansion is caused by reorientation of the C60 molecules. It is assumed that the reorientation is of a quantum character. The inert gas impurities affect the reorientation of the C60 molecules very strongly, especially at liquid helium temperatures. A temperature hysteresis of the thermal expansion coefficient of Kr– and He–C60 solutions has been revealed. The hysteresis is attributed to orientational polyamorphous transformation in these systems.

  • 9. Aleksandrovskii, A. N.
    et al.
    Esel'son, V.B.
    Manzhelii, Vadim Grigorovich
    Udovidchenko, B.G.
    Soldatov, Alexander
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Negative thermal expansion of fullerite C60 at helium temperatures1997In: Low temperature physics (Woodbury, N.Y., Print), ISSN 1063-777X, Vol. 23, no 11, 943-946 p.Article in journal (Refereed)
    Abstract [en]

    The thermal expansion of fullerite C60 has been measured in the temperature range 2–9 K. A compacted fullerite sample with a diameter of about 6 mm and height of 2.4 mm was used. It was found that at temperatures below ~ 3.4 K the linear thermal expansion coefficient becomes negative. At temperatures above 5 K our results are in good agreement with the available literature data. A qualitative explanation of the results is proposed

  • 10. Aleksandrovskii, A. N.
    et al.
    Esel'son, V.B.
    Manzhelii, V.G.
    Udovidchenko, B.G.
    Soldatov, Alexander
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Thermal expansion of single-crystal fullerite C60 at helium temperatures2000In: Low temperature physics (Woodbury, N.Y., Print), ISSN 1063-777X, Vol. 26, no 1, 75-80 p.Article in journal (Refereed)
    Abstract [en]

    The thermal expansion of single-crystal fullerite C60 has been studied in the range of liquid-helium temperatures (2–10 K). At temperatures below ~4.5 K the thermal expansion of fullerite C60 becomes negative, in agreement with the previous results on polycrystalline materials. A qualitative explanation of the results is proposed.

  • 11. Aleksandrovskii, A. N.
    et al.
    Gavrilko, V.G.
    Esel'son, V.B.
    Manzhelii, V. G.
    Udovidchenko, B.G.
    Maletskiy, V.P.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Effect of argon on the thermal expansion of fullerite C60 at helium temperatures2001In: Low temperature physics (Woodbury, N.Y., Print), ISSN 1063-777X, Vol. 27, no 3, 245-246 p.Article in journal (Refereed)
    Abstract [en]

    The linear thermal expansion of compacted Ar-doped fullerite C60(ArxC60) is investigated at 2–12 K using a dilatometric method. The thermal expansion of ArxC60 is also studied after partial desaturation of argon from fullerite. It is revealed that argon doping resulted in a considerable change of the temperature dependence of the thermal expansion of fullerite. An explanation of the observed effects is proposed.

  • 12. Aleksandrovskii, A.N.
    et al.
    Bakai, A.S.
    Cassidy, D.
    Dolbin, A.V.
    Esel'son, V.B.
    Gadd, G.E.
    Gavrilko, V.G.
    Manzhelii, V.G.
    Moricca, S.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    On the polyamorphism of fullerite-based orientational glasses.2005In: Low Temperature Physics, ISSN 1063-777X, Vol. 31, no 5, 429-444 p.Article in journal (Refereed)
    Abstract [en]

    The dilatometric investigation in the temperature range of 2–28 K shows that a first-order

    polyamorphous transition occurs in the orientational glasses based on C60 doped with H2, D2 and

    Xe. A polyamorphous transition was also detected in C60 doped with Kr and He. It is observed that

    the hysteresis of thermal expansion caused by the polyamorphous transition (and, hence, the transition

    temperature) is essentially dependent on the type of doping gas. Both positive and negative

    contributions to the thermal expansion were observed in the low-temperature phase of the glasses.

    The relaxation time of the negative contribution occurs to be much longer than that of the positive

    contribution. The positive contribution is found to be due to phonon and libron modes, whilst the

    negative contribution is attributed to tunneling states of the C60 molecules. The characteristic

    time of the phase transformation from the low-T phase to the high-T phase has been found for the

    C60–H2 system at 12 K. A theoretical model is proposed to interpret these observed phenomena.

    The theoretical model proposed, includes a consideration of the nature of polyamorphism in

    glasses, as well as the thermodynamics and kinetics of the transition. A model of noninteracting

    tunneling states is used to explain the negative contribution to the thermal expansion. The experimental

    data obtained is considered within the framework of the theoretical model. From the theoretical

    model the order of magnitude of the polyamorphous transition temperature has been estimated.

    It is found that the late stage of the polyamorphous transformation is described well by the

    Kolmogorov law with an exponent of n = 1. At this stage of the transformation, the two-dimensional

    phase boundary moves along the normal, and the nucleation is not important.

  • 13. Aleksandrovskii, A.N.
    et al.
    Gavrilko, V.G.
    Esel'son, V.B.
    Manzhelii, V. G.
    Udovidchenko, B.G.
    Maletskiy, V.P.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Thermal expansion of fullerite C60 alloyed with argon and neon2001In: Low temperature physics (Woodbury, N.Y., Print), ISSN 1063-777X, Vol. 27, no 12, 1033-1036 p.Article in journal (Refereed)
    Abstract [en]

    The linear thermal expansion of compacted fullerite C60 alloyed with argon (ArxC60) and neon (NexC60) are investigated by a dilatometric method. The experimental temperature is 2–12 K. In the same temperature interval the thermal expansion of ArxC60 and NexC60 are examined after partial desaturation of the gases from fullerite. It is found that Ar and Ne alloying affects the temperature dependence of the thermal expansion coefficient of C60 quite appreciably. The libration and translation contributions to the thermal expansion of pure C60 are separated. The experimental results on the thermal expansion are used to obtain the Debye temperature of pure C60. The effects observed are tentatively interpreted.

  • 14.
    Al-Hayali, Asifa
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Characterization of ion-irradiation-induced defects in graphite by Raman and Atomic Force Microscopy2013Independent thesis Advanced level (degree of Master (Two Years)), 20 credits / 30 HE creditsStudent thesis
    Abstract [en]

    Graphite is an interesting prototype material for ion implantation studies because of the anisotropy in its physical and structural properties; In particular, due to the layered nature of the graphite lattice, the processes of amorphization and recrystallization (graphitization) of the implanted region are conceptually different from that observed in commonly studied materials. Since ion implantation provides a controlled method for the introduction of lattice defects which can be subsequently annealed, this technique provides fundamental information on the unique crystalline regrowth (graphitization)process of this highly anisotropic material. The structure of ion‐irradiated HOPG has also been studied, and drawing inspiration from this, the crystallite size is fundamental in these novel properties in carbon. The bombarded graphite (with H+ and He ions), diamagnetic graphite, were performed using a Renishaw Raman microscope with a 514.5 nm Ar‐ion laser. The work includes the following parts:

    1. Raman spectroscopy (measurements, spectra treatment with Origin and LabFit program, interpretation based on available literature).

    2. Atomic force microscopy, interpretation with the SPIP software.

    3. TRIM software simulation ion tracks in the sample.

  • 15.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Easterling, Kenneth E.
    Guo, Shi-ju
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Electrical resistivity and critical temperature of Bi-based high-Tc superconductors to 1 GPa1990In: High Pressure Research, volumes 3 to 5: High Pressure Science and Technology: Proceedings of the 12. AIRAPT and 27. EHPRG Conference, University Paderborn 1989, London: Gordon and Breach , 1990, 120-122 p.Conference paper (Refereed)
    Abstract [en]

    We have measured the electrical resistance R of a sintered, two-phase, high-TC superconductor with the nominal composition BiSrCaCu2Ox, as a function of T and p. We find d(lnR)/dp ≃ -0.06 GPa-1 at 295 K, while dTC/dp is 2.5 K/GPa for the phase with Tc ≃ 76 and 2 K/GPa for that with TC ≃ 106 K.

  • 16.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Easterling, Kenneth E.
    Loberg, Bengt
    Niska, John
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    High-pressure properties of high-Tc superconductor samples produced by hot isostatic pressing1990In: High Pressure Research, volumes 3 to 5: High Pressure Science and Technology: Proceedings of the 12. AIRAPT and 27. EHPRG Conference, University Paderborn 1989, London: Gordon and Breach , 1990, 123-126 p.Conference paper (Refereed)
    Abstract [en]

    The electrical resistance of dense YBa2Cu3Ox and YBa2Cu4Oy produced by hot isostatic pressing has been measured vs. T and p. At 295 K we find d (ln R)/dp ≃ -0.12 and -0.09 GPa-1, respectively, with no systematic dependence on initial density. For 1-2-4, dTC/dp ≃ 5.1 K/GPa, which is ten times that of 1-2-3.

  • 17.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Defects and the thermal conductivity of YBa2Cu3O7-d and YBa2Cu4O81993In: Journal of Alloys and Compounds, volume 195: Proceedings of Symposium A on High Tc Superconductors of the 1992 E-MRS Fall Conference, Strasbourg 1992, Elsevier Sequoia S.A. , 1993, 655-658 p.Conference paper (Refereed)
    Abstract [en]

    We present below the first measured data for the thermal diffusivity and the thermal conductivity, λ, of dense, sintered ceramic YBa2Cu4O8 (1-2-4) as a function of temperature T between 40 and 310 K. At 300 K, λ is 6.3 Wm−1K−1, increasing with decreasing T to about 9.5 Wm−1K−1 near Tc. This T dependence is much stronger than in YBa2Cu3O7−δ (1-2-3). Only a very small enhancement is observed in λ below Tc. As in 1-2-3, λ is mainly limited by phonon scattering by defects.

  • 18.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Thermal conductivity and thermal diffusivity of dense, bulk YBa2Cu4O81994In: High Temperatures - High Pressures volume 26, issue 1: Proceedings of the 13th European Conference on Thermophysical Properties (13 ECTP), Lisboa 1993, London: Pion Press , 1994, 53-57 p.Conference paper (Refereed)
    Abstract [en]

    We have measured the thermal conductivity, lambda, and the thermal diffusivity, a, of dense bulk ceramic YBa2Cu4O8 (1-2-4) between 30 and 300 K. For this material lambda is about 10 W/Km near 100 K, comparable with the in-plane thermal conductivity for single crystals of the more common high-Tc material YBa2Cu3O7 (1-2-3). Also, lambda has a much stronger T dependence in 1-2-4 than in 1-2-3. We find that, for 1-2-4, lambda can be very well described by a semiclassical phonon theory, which includes phonon, electron, and boundary scattering. The difference between the present results and those for 1-2-3 can be explained mainly in terms of a smaller amount of point-defect scattering in 1-2-4 because of the stable oxygen stoichiometry of this material.

  • 19.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Thermal conductivity of YBa2Cu4O8 dominated by phonon-phonon interactions1993In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, Vol. 48, no 5, 3575-3578 p.Article in journal (Refereed)
    Abstract [en]

    The thermal conductivity κ of dense sintered ceramic YBa2Cu4O8 in the range 30–310 K has been measured. At 100 K, κ is 10 W m-1 K-1, approaching the in-plane κ of single crystals of other high-Tc materials. κ decreases rapidly with increasing T to 7.4 W m-1 K-1 at 300 K. Fitting standard models for κ(T) to the data we find that κ is limited mainly by phonon-phonon interactions. Depending on the model used, the best fit is found for effective values of FTHETADebye between 155 and 185 K, characteristic for the acoustic phonon branches, indicating that such phonons carry most of the heat. Finally, we suggest a possible way to test the electron-phonon model for the electrical and thermal conductivities in high-Tc materials.

  • 20.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Thermal conductivity of YBa2Cu4O8 under high pressure1993In: Physica. C, Superconductivity, ISSN 0921-4534, Vol. 216, no 1-2, 187-194 p.Article in journal (Refereed)
    Abstract [en]

    The thermal diffusivity a of YBa2Cu4O8 (1-2-4) has been measured as a function of pressure p and temperature T over the range 85<T<310 K and up to 1 GPa (10 kbar). From the data obtained we have calculated the pressure dependence of the thermal conductivity κ as a function of T. κ increases slowly with increasing p above 150 K but decreases below this value. Most of the high-T increase with p is caused by an increase in the electronic thermal conductivity κe. For the phonon thermal conductivity, which dominates κ in 1-2-4, we find that charge transfer with p causes a strong increase in electron-phonon scattering with p, while the p dependence of the boundary scattering and phonon-phonon scattering is in reasonable agreement with the behaviour predicted by simple models.

  • 21.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Thermal diffusivity and thermal conductivity of YBa2Cu3O7-d and YBa2Cu4O8 between 20 and 300 K1992In: Proceedings of the Joint Nordic Spring Meeting '92 / [ed] Per-Anker Lindgård, Roskilde: Risö National Laboratory/Grafisk Service, Risö , 1992, 251- p.Conference paper (Other academic)
  • 22.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Niska, John
    Loberg, Bengt
    Thermal conductivity of polycrystalline YBa2Cu4O81994In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, Vol. 49, no 6, 4189-4198 p.Article in journal (Refereed)
    Abstract [en]

    We have measured the thermal conductivity κ and the thermal diffusivity a of a dense bulk ceramic polycrystalline sample of YBa2Cu4O8 (1:2:4) in the temperature range 30–300 K. We find κ≊10 W m-1 K-1 at 100 K, significantly higher than in ceramic YBa2Cu3O7-δ (1:2:3) and approaching the in-plane value for single-crystal 1:2:3, and decreasing to 7.6 W m-1 K-1 at 300 K. The data for this sample can be described by standard theories for phonon thermal conductivity of crystalline materials with boundary, phonon, and electron scattering. The higher κ in 1:2:4 as compared to 1:2:3 is, in this model, due to the smaller point defect scattering in the former. The fitted parameters for the three scattering mechanisms all agree with independent estimates based on simple models; inserting data for electric resistivity, grain size, carrier density, and lattice properties we can predict κ and its T dependence to within about 20%. We also discuss models for the phonon and electron thermal conductivities in some detail, including some second-order effects such as inelastic electron scattering and a T-dependent carrier density.

  • 23.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Niska, John
    Loberg, Bengt
    Easterling, Kenneth
    Electrical transport in dense, bulk YBa2Cu4O8 produced by hot isostatic pressing1990In: Physica B Volumes 165 & 166, Part 2: LT-19 Part II: Contributed Papers, Proceedings of the 19th International Conference on Low Temperature Physics, Brighton 1990, Elsevier B.V. , 1990, 1699-1700 p.Conference paper (Refereed)
    Abstract [en]

    Dense (98.5%) bulk sintered specimens of YBa2Cu4O8 have been produced by hot isostatic pressing. Data for the electrical resistivity π versus temperature T and pressure p in the range 70–300 K and 0–0.7 GPa are reported and discussed. The critical current density of the material studied exceeds 100 Acm−2 below 60 K.

  • 24.
    Andersson, Britt M.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Niska, John
    Loberg, Bengt
    Easterling, Kenneth
    Electrical transport properties of dense bulk YBa2Cu4O8 produced by hot isostatic pressing1990In: Physica. C, Superconductivity, ISSN 0921-4534, Vol. 170, no 5-6, 521-531 p.Article in journal (Refereed)
    Abstract [en]

    Highly dense sintered YBa2Cu4O8 has been produced by hot isostatic pressing (HIP). The electrical resistivity varrho of this material has been measured as a function of temperature T and pressure varrho in the range 40–650 K and 0–0.7 GPa. Both the temperature dependence and the pressure dependence of varrho are found to be well described by a model based on the standard Bloch-Grüneisen theory. It is pointed out that varrho is liner in T only under isobaric conditions, while varrho is strongly nonlinear in all high-Tc superconductors under isochoric (constant volume) conditions. The critical current density of the material is 900 A/cm2 at 4 K, while the resistivity is 630 μΩ cm at 294 K.

  • 25.
    Andersson, Göran
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Pressure dependence of the c-axis resistance of stage 2 SbCl5 intercalated graphite to 4 GPa1988In: Solid State Communications, ISSN 0038-1098, Vol. 65, no 7, 735-738 p.Article in journal (Refereed)
    Abstract [en]

    The c-axis electrical resistance R has been measured under pressure up to 4 GPa (40 kbar) at room temperature for stage 2, HOPG-based SbCl5 intercalated graphite. In addition to the well known ordering transition at 0.3–0.5 GPa a second anomaly in R is observed above 1 GPa, corresponding to a further phase transition which is not completed until above 2.4 GPa. In all phases R depends more strongly on p for the intercalated material than for HOPG, and the total decrease in R is over 80% to 4 GPa.

  • 26.
    Andersson, Göran
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Bäckström, Gunnar
    Umeå University, Faculty of Science and Technology, Physics.
    A high-pressure cell for electrical resistance measurements at hydrostatic pressures up to 8 GPa: Results for Bi, Ba, Ni, and Si1989In: Journal of Applied Physics, ISSN 0021-8979, Vol. 65, no 10, 3943-3950 p.Article in journal (Refereed)
    Abstract [en]

    A modified Bridgman anvil high-pressure device, capable of producing hydrostatic pressures up to 8 GPa (80 kbar), was designed and built. The size of the pressure chamber (10 mm in diameter) allows the use of large specimens and simple experimental procedures. Experimental results show that hydrostatic conditions are necessary if accurate quantitative information is desired about the electrical properties of materials under pressure. Accurate data on resistance (and resistivity) versus pressure at 294 K are given for Bi, Ba, Ni, and Si. The initial pressure coefficients of R were d(ln R)dP=0.13, −7.6×10−2, −2.0×10−2, and −0.26 GPa−1, respectively. Barium has a resistance minimum near 0.9 GPa. For Bi we observe sharp transitions at 2.55, 2.7, and 7.7 GPa, and for Ba at 5.55 GPa, but we cannot verify the existence of a transition in Ba near 7 GPa. Neither do we confirm the phase transformation in Ni recently reported to occur above 2.5 GPa. For Si, R(P) agrees very well with a theoretical function calculated from the change in band gap and electron mobility with pressure.

  • 27.
    Andersson, Göran
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Bäckström, Gunnar
    Umeå University, Faculty of Science and Technology, Physics.
    Electrical resistivity measurements under hydrostatic conditions up to 10 GPa1984In: Journal de Physique Colloques vol. 45: Supplément C8, Physics and Physicochemistry of Highly Condensed Matter; Proceedings of the XXIInd Meeting of the EHPRG, Aussois, Sept. 1984, 1984, 379-382 p.Conference paper (Refereed)
    Abstract [en]

    A large scale Bridgman anvil system has been designed. Steel gaskets permit compression of a methanol-ethanol medium over a volume of 500-250 mm3. Up to 12 wires have been used to contact specimens. The system has so far served up to 7.5 GPa, with anvils made of ASP tool steel. The transition Bi III-V was found to occur at a lower pressure than the recommended average. The electrical resistance of copper was measured up to 6 GPa under hydrostatic conditions.

  • 28.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Behrens, Peter
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    C-axis resistance of HgCl2 intercalated graphite as a function of temperature and pressure1989In: Synthetic Metals volume 34: Proceedings of the Fifth International Symposium on Intercalated Graphite, Berlin (West) 1989, Lausanne: Elsevier Sequoia SA , 1989, 485-490 p.Conference paper (Refereed)
    Abstract [en]

    The c-axis resistance of stage 3 HgCl2 intercalated graphite has been measured as a function of temperature T and pressure p in the range 40 to 300 K and up to 1 GPa (10 kbar). The absolute resistivity and its T- and p- dependence are all in good agreement with data for other acceptor compounds. The measurements show that a previosly unknown phase transformation occurs above 0.4 GPa. Below 250 K the high pressure phase is metastable down to zero pressure, and an x-ray diffraction analysis of metastable material shows that no stage change occurs. The transition thus probably leads to a different in-plane structure characterized by a more densely packed intercalate layer.

  • 29.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Lelaurain, Michelle
    Marêché, Jean-Francois
    McRae, Edward
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Pressure-induced modifications of structural and transport properties in SbCl5 intercalated graphite1992In: Materials Science Forum volumes 91-93, Part I: Intercalation Compounds ISIC-6: Proceedings of the Sixth International Symposium on Intercalation Compounds, Orléans 1991., Zürich: Trans Tech Publications , 1992, 301-306 p.Conference paper (Refereed)
    Abstract [en]

    The structure and the c-axis resistivity of SbCl5 intercalated graphite have been studied as functions of T and p, over the ranges 40 to 295 K and 0 to 0.7 GPa. Slow cooling or slow application of pressure p > 0.4 GPa lead to states of complete but different crystallization of the intercalate, but after rapid cooling or pressurization any crystallization is incomplete. The resistivity of the high pressure crystallized phase is about 50% lower than that of the low T, low p phase under identical p-T conditions. No significant difference is seen between the behaviour of HOPG-based and single crystal based materials.

  • 30.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Lelaurain, Michelle
    Marêché, Jean-Francois
    McRae, Edward
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Structure, c-axis resistivity, and p-T phase diagram of SbCl5 intercalated graphite1989In: Synthetic Metals volume 34: Proceedings of the Fifth International Symposium on Intercalated Graphite, Berlin (West) 1989, Lausanne: Elsevier Sequoia SA , 1989, 187-192 p.Conference paper (Refereed)
    Abstract [en]

    Experimental data are reported for the c-axis resistivity varrhoc of stages n = 3,4,5 and 8 SbCl5 intercalated graphite as a function of T and p, in the range 40 – 300 K and 0-0.5 GPa (5 kbar). varrhoc varied in a systematic way with p, T, and n. Well ordered low-T phases were obtained for all stages; disordering at 200 – 235 K gave rise to well defined multiple anomalies in varrhoc. We also report x-ray diffraction data on the stage 2 compound: evidence was found for large variations in the in-plane structure even for nominally identical samples.

  • 31.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    McRae, Edward
    Lelaurain, Michelle
    Marêché, Jean-Francois
    A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part IV: Basal plane resistivity1995In: Journal of Materials Research, ISSN 0884-2914, Vol. 10, no 7, 1653-1660 p.Article in journal (Refereed)
    Abstract [en]

    Using an inductive technique, we have measured the in-plane resistivity rhoa of stages 2, 4, 5, and 8 SbCl5-GIC's versus temperature T and pressure p in the ranges 130–300 K and 0–0.85 GPa. The room temperature values of rhoa range from 4.0 µOcm for the stages 5 sample to 7.7 µOcm for the stage 8 sample. At all pressures, rhoa shows a metallic temperature dependence rhoa ~ Ta, with 1 < a < 2, but in contrast to the c-axis resistivity rhoc, it depends only very weakly on pressure and/or intercalate structural order. We show that the behavior observed is consistent with a band conduction model.

  • 32.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    McRae, Edward
    Marêché, Jean-Francois
    Lelaurain, Michelle
    A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part II. Experimental data for c-axis resistivity1992In: Journal of Materials Research, ISSN 0884-2914, Vol. 7, no 11, 2989-3000 p.Article in journal (Refereed)
    Abstract [en]

    We present experimental data for the c-axis resistivity ?c of stage s = 2, 3, 4, 5, and 8, SbCl5 intercalated graphite, over the temperature range 40 to 300 K and the pressure range 0 to 0.8 GPa (0–8 kbar). For most specimens studied, resistance anomalies are observed below 230 K at atmospheric pressure and at pressures up to 0.5 GPa at 293 K. These anomalies are explained in terms of structural changes from a disordered or partly crystallized in-plane intercalate structure at atmospheric pressure and T > 230 K to an almost completely crystallized structure below this temperature, or at elevated pressures, as discussed in a companion paper. In the crystallized phases ?c is approximately linear in T except for stage 8, for which a nonlinear behavior, with a negative temperature coefficient of resistivity below 200 K, is observed. The results are compared with previously available literature data, and the p-T phase diagram is briefly discussed.

  • 33.
    Andersson, Odd E.
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Polo, V.
    Vangelisti, René
    Marêché, Jean Francois
    McRae, Edward
    The c-axis resistivity for two HOPG-based, first stage CuAl2Cl8 and second stage CuCl2 - graphite intercalation compounds as a function of both pressure and temperature1996In: Journal of Physics and Chemistry of Solids, volume 57, issues 6-8: Proceedings of the 8th International Symposium on Intercalation Compounds (ISIC-8), Vancouver 1995, Elsevier Ltd. , 1996, 719-723 p.Conference paper (Refereed)
    Abstract [en]

    In this paper we present data for the c-axis resistivity of first stage CuAl2Cl8 GIC and second stage CuCl2 GIC as functions of pressure, p, (0.0 < p < 1.5 GPa) and of temperature, T, (4 < T < 300 K). We show evidence of a possible new high-pressure phase above 1.0 GPa for the CuAl2Cl8 GIC and we show that the CuCl2 GIC is very stable at all pressures and temperature investigated. We make a comparison with previous results on SbCl5 GICs and other chloride intercalation compounds and with theories treating the temperature and pressure coefficients of transport parameters in layered solids.

  • 34.
    Andersson, Ove
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Glass-liquid transition of water at high pressure2011In: Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, E-ISSN 1091-6490, Vol. 108, no 27, 11013-11016 p.Article in journal (Refereed)
    Abstract [en]

    The knowledge of the existence of liquid water under extreme conditions and its concomitant properties are important in many fields of science. Glassy water has previously been prepared by hyperquenching micron-sized droplets of liquid water and vapor deposition on a cold substrate (ASW), and its transformation to an ultraviscous liquid form has been reported on heating. A densified amorphous solid form of water, high-density amorphous ice (HDA), has also been made by collapsing the structure of ice at pressures above 1 GPa and temperatures below approximately 140 K, but a corresponding liquid phase has not been detected. Here we report results of heat capacity C(p) and thermal conductivity, in situ, measurements, which are consistent with a reversible transition from annealed HDA to ultraviscous high-density liquid water at 1 GPa and 140 K. On heating of HDA, the Cp increases abruptly by (3.4 ± 0.2) J mol-1 K-1 before crystallization starts at (153 ± 1) K. This is larger than the Cp rise at the glass to liquid transition of annealed ASW at 1 atm, which suggests the existence of liquid water under these extreme conditions.

  • 35.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Chobal, Oleksandr
    Department of Solid State Electronics, Uzhhorod National University, Ukraine.
    Rizak, I
    Department of Integrated Technologies of Aviation Manufacture, National Aerospace University of “KhAI", Kharkov, Ukraine.
    Rizak, V
    Department of Solid State Electronics, Uzhhorod National University, Ukraine.
    Tricritical Lifshitz point in the temperature-pressure-composition diagram for (PbySn1-y)2 P2(SexS1-x)6 ferroelectrics2009In: Physical Review B Condensed Matter, ISSN 0163-1829, E-ISSN 1095-3795, Vol. 80, 174107- p.Article in journal (Refereed)
    Abstract [en]

    The heat capacity of Sn2P2S6 ferroelectric crystals has been measured under quasihydrostatic pressures up to 0.7 GPa. The analysis of the heat-capacity and literature data for the birefringence shows that the tricritical point of Sn2P2S6 is in the 0.20–0.25 GPa range. Moreover, in the approximation of a linear change in the free-energy expansion coefficients, with respect to concentration and pressure, thermodynamic trajectories have been constructed for (PbySn1−y)2 P2(SexS1−x)6 solid solutions. We have thereby identified the region of the T-p-y-x diagram for (PbySn1−y)2 P2(SexS1−x)6 showing the tricritical Lifshitz point.

  • 36.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Filinchuk, Yaroslav
    Dmitriev, Vladimir
    Quwar, Issam
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Talyzin, Alexandr
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Phase coexistence and hysteresis effects in the pressure-temperature phase diagram of NH3BH32011In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 84, no 2, 024115- p.Article in journal (Refereed)
    Abstract [en]

    The potential hydrogen storage compound NH3BH3 has three known structural phases in the temperature and pressure ranges 110–300 K and 0–1.5 GPa, respectively. We report here the boundaries between, and the ranges of stability of, these phases. The phase boundaries were located by in situ measurements of the thermal conductivity, while the actual structures in selected areas were identified by in situ Raman spectroscopy and x-ray diffraction. Below 0.6 GPa, reversible transitions involving only small hysteresis effects occur between the room-temperature tetragonal plastic crystal I4mm phase and the low-temperature orthorhombic Pmn21 phase. Transformations of the I4mm phase into the high-pressure orthorhombic Cmc21 phase, occurring above 0.8 GPa, are associated with very large hysteresis effects, such that the reverse transition may occur at up to 0.5 GPa lower pressures. Below 230 K, a fraction of the Cmc21 phase is metastable to atmospheric pressure, suggesting the possibility that dense structural phases of NH3BH3, stable at room temperature, could possibly be created and stabilized by alloying or by other methods. Mixed orthorhombic Pmn21/Cmc21 phases were observed in an intermediate pressure-temperature range, but a fourth structural phase predicted by Filinchuk et al. [ Phys. Rev. B 79 214111 (2009)] was not observed in the pressure-temperature ranges of this experiment. The thermal conductivity of the plastic crystal I4mm phase is about 0.6 W m−1 K−1 and only weakly dependent on temperature, while the ordered orthorhombic phases have higher thermal conductivities limited by phonon-phonon scattering.

  • 37.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Inaba, Akira
    Unusual Grüneisen and Bridgman parameters of low-density amorphous ice and their implications on pressure induced amorphization2005In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 122, no 12, 124710- p.Article in journal (Refereed)
    Abstract [en]

    The low-temperature limiting value of the Grüneisen parameter for low-frequency phonons and the density dependence of the thermal conductivity (Bridgman parameter) of low-density amorphous (LDA) ice, high-density amorphous (HDA) ice, hexagonal ice Ih, and cubic ice Ic were calculated from high-pressure sound velocity and thermal conductivity measurements, yielding negative values for all states except HDA ice. LDA ice is the first amorphous state to exhibit a negative Bridgman parameter, and negative Grüneisen parameters are relatively unusual. Since Ih, Ic, and LDA ice all transform to HDA upon pressurization at low temperatures and share the unusual feature of negative Grüneisen parameters, this seems to be a prerequisite for pressure induced amorphization. We estimate that the Grüneisen parameter increases at the ice Ih to XI transition, and may become positive in ice XI, which indicates that proton-ordered ice XI does not amorphize like ice Ih on pressurization.

  • 38.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, G P
    Sub-Tg features of glasses formed by cooling glycerol under pressure – Additional incompatibility of vibrational with configurational states in the depressurized, high density glass2016In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 145, 204506Article in journal (Refereed)
    Abstract [en]

    The vibrational state of a glass is naturally incompatible with its configurational state, which makes the glass structurally unstable. When a glass is kept at constant temperature, both the vibrational and configurational states of a glass change with time until it becomes metastable (equilibrium) liquid and the two states become compatible. The process, known as structural relaxation, occurs at a progressively higher rate during heating, and the properties of a glass change accordingly. We add to this incompatibility by depressurizing a glass that had been formed by cooling a liquid under a high pressure, p, and then investigate the effects of the added incompatibility by studying thermal conductivity, κ, and the heat capacity per unit volume ρCp of the depressurized glass.We use glycerol for the purpose and study first the changes in the features of κ and of ρCp during glass formation oncooling under a set of different p. We then partially depressurize the glass and study the effect of the p-induced instability on the features of and Cp as the glass is isobarically heated to the liquid state.At a given low p, the glass configuration that was formed by cooling at high-p had a higher κ than the glass configuration that was formed by cooling at a low p. The difference is more when the glass is formed at a higher p and/or is depressurized to a lower p. On heating at a low p, its κ decreases before its glass-liquid transition range is reached. The effect is the opposite of the increase in observed on heating a glass at the same p under which it was formed. It is caused by thermally assisted loss of the added incompatibility of configurational and vibrational states of a high-p formed glass kept at low p. If a glass formed under a low-p is pressurized and then heated under high p, it would show the opposite effect, i.e., its κ would first increase to its high p value before its glass-to-liquid transition range.

  • 39.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, Gyan P
    Effect of pressure on thermal conductivity and pressure collapse of ice in a polymer-hydrogel and kinetic unfreezing at 1 GPa2011In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 134, no 12, 124903- p.Article in journal (Refereed)
    Abstract [en]

    We report a study of aqueous solutions of poly(vinylalcohol) and its hydrogel by thermal conductivity,κ, and specific heat measurements. In particular, we investigate (i) the changes in the solution and the hydrogel at 0.1 MPa observed in the 350-90 K range and of the frozen hydrogel at 130 K observed in the range from 0.1 MPa to 1.3 GPa, and (ii) the nature of the pressure collapse of ice in the frozen hydrogel and kinetic unfreezing on heating of its high density water at 1 GPa. The water component of the polymer solution on cooling either first phase separates and then freezes to hexagonal ice or freezes without phase separation and the dispersed polymer chains freeze-concentrate in nanoscopic and microscopic regions of the grain boundaries and grain junctions of the ice crystals in the frozen state of water in the hydrogel. The change in κ with temperature at 1 bar is reversible with some hysteresis, but not reversible with pressure after compression to 0.8 GPa at 130 K. At high pressures the crystallized state collapses showing features of. and specific heat characteristic of formation of high density amorphous solid water. The pressure of structural collapse is 0.08 GPa higher than that of ice at 130 K. The slowly formed collapsed state shows kinetic unfreezing or glass-liquid transition temperature at 140 K for a time scale of 1 s. Comparison with the change in the properties observed for ice shows that κ decreases when the polymer is added. 

  • 40.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, Gyan P
    Department of Materials Science and Engineering, McMaster University, Hamilton, Canada.
    Pressure-induced collapse of ice clathrate and hexagonal ice mixtures formed by freezing2009In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 131, 114503-114513 p.Article in journal (Refereed)
    Abstract [en]

    We report thermal conductivity κ measurements of the pressure-induced collapse of two mixtures of ice and tetrahydrofuran (THF) clathrate hydrate formed by freezing aqueous solutions, THF·23 H2O and THF·20 H2O, one containing twice as much excess water than the other. On pressurizing, κ of the solid mixture first decreases at the onset pressure of 0.8 GPa, as occurs for collapse of pure ice, reaches a local minimum at a pressure of 1.0 GPa, and then increases as occurs for the collapse of the pure clathrate THF·17 H2O. This shows that in the apparently homogeneous mixture, the ice and the clathrate collapse as if the two were in a mechanically mixed state. The manner in which the clathrate aggregate can arrange in the solid indicates that ice occupies the interstitial space in the tightly packed aggregates and H2O molecules belonging to the lattice of one form hydrogen bond with that of the other, a feature that is preserved in their collapsed states. On decompression, the original clathrate is partially recovered in the THF·20 H2O mixture, but the collapsed ice does not transform to the low density amorph. We surmise that on irreversible transformation to the original clathrate, the aggregates expand. Any pressure thus exerted on the small domains of the collapsed ice with a hydrogen bonded interface with the clathrate aggregates could prevent it from transforming to the low density amorph. Measurements of κ are useful in investigating structural collapse of crystals when dilatometry is unable to do so, as κ seems to be more sensitive to pressure-induced changes than the volume.

  • 41.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, Gyan P
    Spontaneous transformation of water's high-density amorph and a two-stage crystallization to ice VI at 1 GPa: a dielectric study2004In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 120, no 24, 11662-11671 p.Article in journal (Refereed)
    Abstract [en]

    Dielectric relaxation spectra of a metastable crystal phase formed on implosive and exothermic transformation of pressure-amorphized hexagonal ice have been measured in situ at 0.97 GPa pressure over a range of temperature. The metastable phase showed no relaxation peak at 130 K and 0.97 GPa. When heated at a fixed pressure of 0.97 GPa, it began to transform at ∼ 145 K exothermally to a phase whose relaxation rate and equilibrium dielectric permittivity increased. A second, but slower exothermic transformation also occurred at ∼ 175 K. After keeping at 213 K, the relaxation rate and equilibrium permittivity reached the known values of these two quantities for ice VI. Thus the metastable phase transformed to ice VI in two stages. It is conjectured that the intermediate phase in this transformation could be ice XII. The rate of transformation is not determined by the reorientational relaxation rate of water molecules in the ices

  • 42.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, Gyan P
    Time-dependent amorphization of ice at 0.8-0.9 GPa2004In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 121, no 8, 3936-3938 p.Article in journal (Refereed)
    Abstract [en]

    Thermal conductivity measurements show that ice continues to amorphize for several days when kept at a fixed pressure p in the 0.79–0.88 GPa range, and fixed temperature T in the 127–130 K range. Thermal conductivity k decreases according to a stretched exponential in time, and its limiting long time value k() varies with p and T. At 0.8 GPa and 128 K, k() remains 2.5 times the value observed for high-density amorph. Consequences of these findings for our understanding of amorphization are discussed.

  • 43.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Johari, Gyan P
    Suga, H.
    An ice phase of lowest thermal conductivity2004In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 120, no 20, 9612-9617 p.Article in journal (Refereed)
    Abstract [en]

    On pressurizing at temperatures near 130 K, hexagonal and cubic ices transform implosively at 0.8–1 GPa. The phase produced on transformation has the lowest thermal conductivity among the known crystalline ices and its value decreases on increase in temperature. An ice phase of similar thermal conductivity is produced also when high-density amorphous ice kept at 1 GPa transforms on slow heating when the temperature reaches ∼155 K. These unusual formation conditions, the density and its distinguished thermal conductivity, all indicate that a distinct crystal phase of ice has been produced.

  • 44.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Soldatov, Alexander
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Reorientational relaxation in C60 following a pressure induced change in the pentagon/hexagon equilibrium ratio1995In: Physics Letters A, ISSN 0375-9601, Vol. 206, no 3-4, 260-264 p.Article in journal (Refereed)
    Abstract [en]

    The orientational structure of C60 depends on pressure and temperature. Pressurization below the glass transition temperature Tg can freeze in non-equilibrium orientational structures. The relaxation of such structures on heating through Tg has been studied through thermal conductivity measurements and the effects observed are explained in a simple model.

  • 45.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Soldatov, Alexander
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Thermal conductivity of C60 at pressures up to 1 GPa and temperatures in the range 50-300 K1996In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, Vol. 54, no 5, 3093-3100 p.Article in journal (Refereed)
    Abstract [en]

    The thermal conductivity λ of C60 shows anomalies near 260 K and 90 K which are associated with the well-established phase transition and glass transition, respectively. Both transition temperatures increase with pressure, at the rates 120 K GPa-1 and 62 K GPa-1, respectively. With increasing temperature, λ of the simple cubic (sc) phase increased below 170 K (glasslike behavior) but decreased above. The glasslike behavior of λ is probably due to a substantial amount of lattice defects. Possible reasons for the change of sign of dλ/dT near 170 K are discussed. In the face centered cubic (fcc) phase (T≳260 K at atmospheric pressure) λ was almost independent of temperature, a behavior which is far from that of an ordered crystal (λ∝T-1 for T≳Debye temperature). This result can be attributed to the molecular orientational disorder of the fcc phase. The relaxation behavior associated with the glassy state and its unusually strong dependence on thermal history are discussed briefly, and data which support a previously reported relaxation model are presented. At room temperature, the density dependencies of λ, (∂ lnλ/∂ lnρ)T, were 5.5 and 9.5 for the fcc and sc phases, which are values typical for an orientationally disordered phase and a normal crystal phase, respectively.

  • 46.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Soldatov, Alexander
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Thermal conductivity of C60 under high pressure1995In: Science and Technology of Fullerene Materials: Materials Research Society Symposium Proceedings vol. 359, Pittsburgh, PA: Materials Research Society , 1995, 549-554 p.Conference paper (Refereed)
    Abstract [en]

    We have measured the thermal conductivity lambda of highly pure polycrystalline C60 in the range 50 to 300 K under pressures up to 1 GPa. The results are discussed in terms of the lattice structure and dynamics. In particular, we discuss the phase diagram as delineated by anomalies observed in lambda and cp at the f.c.c.-to-s.c. transition at 260 K and the glass transition at Tg = 90 K, and also the effect on lambda of the orientational motion in the s.c. phase. The results are found to be compatible with a p/T phase diagram recently suggested by us.

  • 47.
    Andersson, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Bäckström, Gunnar
    Umeå University, Faculty of Science and Technology, Physics.
    A low-temperature high-pressure apparatus with a temperature control system1992In: High Pressure Research, ISSN 0895-7959, Vol. 10, no 4, 599-606 p.Article in journal (Refereed)
    Abstract [en]

    A low-temperature high-pressure apparatus was designed using commercial cryogenic equipment. Pressures up to 1 GPa and temperatures down to 40 K can be obtained in a volume of up to 30 cm3. The apparatus is of the piston-cylinder type with a piston diameter of 45 mm, and the pressure can be varied at all temperatures, An adaptive temperature control system keeps the temperature inside the pressure cylinder constant to within ±0.1 K.

  • 48.
    Andersson, Per
    et al.
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Pressure dependence of the thermal conductivity, thermal diffusivity, and specific heat of some polymers1975In: Journal of Polymer Science Polymer Physics Edition, ISSN 1542-9385, Vol. 13, no 2, 243-251 p.Article in journal (Refereed)
    Abstract [en]

    The pressure dependence of the specific heat of poly(methyl methacrylate), polystyrene, and atactic and isotactic polypropylene was determined from simultaneous measurements of thermal conductivity and diffusivity in a cylindrical geometry at 300°K and in the pressure range 0-37 kbar. The thermal conductivity and the diffusivity both increase strongly with pressure, while the specific heat decreases. The pressure dependencies are most pronounced at low pressures. The results are compared with other experimental results and with theoretical calculations.

  • 49. Araújo, C. Moysés
    et al.
    Ahuja, Rajeev
    Talyzin, Alexandr V
    Umeå University, Faculty of Science and Technology, Physics.
    Sundqvist, Bertil
    Umeå University, Faculty of Science and Technology, Physics.
    Pressure-induced structural phase transition in NaBH42005In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, Vol. 72, no 5, 054125- p.Article in journal (Refereed)
    Abstract [en]

    We present a combined experimental and theoretical study of the technologically important NaBH4 compound under high pressure. Using Raman spectroscopy at room temperature, we have found that NaBH4 undergoes a structural phase transformation starting at 10.0 GPa with the pure high-pressure phase being established above 15.0 GPa. In order to compare the Raman data recorded under high pressure with the low-temperature tetragonal phase of NaBH4, we have also performed a cooling experiment. The known order-disorder transition from the fcc to the tetragonal structure was then observed. However, the new high pressure phase does not correspond to this low-temperature structure. Using first-principle calculations based on the density functional theory, we show that the high-pressure phase corresponds to the alpha-LiAlH4–type structure. We have found a good agreement between the measured and calculated transition pressures. Additionally, we present the electronic structure of both the fcc and the high-pressure phases.

  • 50.
    Axner, Ove
    et al.
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Björnham, Oscar
    Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
    Castelain, Mickaël
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Koutris, Efstratios
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Schedin, Staffan
    Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
    Fällman, Erik
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Andersson, Magnus
    Umeå University, Faculty of Science and Technology, Department of Physics.
    Unraveling the secrets of bacterial adhesion organelles using single molecule force spectroscopy2010In: Springer series in chemical physics: single molecule spectroscopy in chemistry, physics and biology, Springer Verlag , 2010, 96, 337-362 p.Chapter in book (Other academic)
    Abstract [en]

    Many types of bacterium express micrometer-long attachment organelles (so called pili) whose role is to mediate adhesion to host tissue. Until recently, little was known about their function in the adhesion process. Forcemeasuring  ptical tweezers (FMOT) have since then been used to unravel the  iomechanical properties of various types of pili, primarily those from uropathogenic E. coli, in particular their force-vs.-elongation response, but lately also some properties of the adhesin situated and the distal end of the pilus. This knowledge provides an understanding of how piliated bacteria can sustain external shear forces caused by rinsing processes, e.g. urine flow. It has been found that anytypes of pilus exhibit unique and complex force-vs.-elongation responses. It has been conjectured that their dissimilar properties impose significant differences in their ability to sustain external forces and that different types of pilus therefore have dissimilar predisposition to withstand different types of rinsing conditions. An understanding of these properties is of high importance since it can serve as a basis for finding new means to combat bacterial adhesion, including that caused by antibiotic-resistance bacteria. This work presents a review of the current status of the assessment of biophysical properties of individual pili on single bacteria exposed to strain/stress, primarily by the FMOT technique. It also addresses, for the first time, how the elongation and retraction properties of the rod couple to the adhesive properties of the tip adhesin.

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